Tetramethyl Orthosilicate
Everything that changed this substance, across every flow that resolves to it. Back to the substance
fo-b3c30ff19a4752b4
Changes
54| # | Step | Field | From | To | Why |
|---|---|---|---|---|---|
| 13,858 | bootstrap_labels | prefLabel | — | [{"@value":"tetramethyl orthosilicate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:wasAtt… | Bootstrapped prefLabel from legacy name field |
| 13,859 | bootstrap_labels | name | tetramethyl orthosilicate | — | Purged legacy name field to enforce prefLabel usage |
| 13,860 | bootstrap_labels | synonyms | ["organometallic","tetramethylorthosilicate","dynasylan(r)m"] | [] | Removed legacy synonyms field in favor of structured labels |
| 48,493 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Aircraft cruise height"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to lower stratosphere and upper troposphere |
| 48,494 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-aicrhe | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to lower stratosphere and upper troposphere |
| 100,669 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Water","water_body":"Long-term"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to water, unspecified (long-term) |
| 100,670 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-wate-lote | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to water, unspecified (long-term) |
| 105,157 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Unknown"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified |
| 105,158 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-unkn | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified |
| 126,787 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Ground","geography":"Agricultural"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to agricultural soil |
| 126,788 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-grou-agri | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to agricultural soil |
| 133,669 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Medium stack, <150 meters","population_density":"Rural (<1000 peop… | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to non-urban air or from high stacks |
| 133,670 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-mest15me-ru10pesq | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to non-urban air or from high stacks |
| 151,331 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Long-term"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified (long-term) |
| 151,332 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-lote | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified (long-term) |
| 153,399 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","indoor":"Unknown"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, indoor |
| 153,400 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-indr-unkn | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, indoor |
| 156,665 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Ground","geography":"Unknown"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to soil, unspecified |
| 156,666 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-grou-unkn | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to soil, unspecified |
| 161,823 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Water","water_body":"Unknown"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to water, unspecified |
| 161,824 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-wate-unkn | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to water, unspecified |
| 163,971 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Water","water_body":"Ocean"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to sea water |
| 163,972 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-wate-ocea | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to sea water |
| 194,169 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Ground level","population_density":"Urban (>1000 people/square mil… | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to urban air close to ground |
| 194,170 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-grle-ur10pesq | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to urban air close to ground |
| 202,263 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Water","water_body":"Surface water"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to fresh water |
| 202,264 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-wate-suwa | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to fresh water |
| 213,131 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Ground","geography":"Non-agricultural"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to non-agricultural soil |
| 213,132 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-grou-noag | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to non-agricultural soil |
| 217,920 | unit_normalization | unit_iri | — | https://vocab.brightway.one/units/unit/KiloGM | Unit IRI set from normalization of 'kg' |
| 224,309 | normalize_name_case | prefLabel | [{"@value":"tetramethyl orthosilicate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:wasAtt… | [{"@value":"Tetramethyl Orthosilicate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:wasAtt… | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| 240,309 | enrich_references | properties | {} | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C4H12O4Si"… | Added ChEBI/PubChem properties (chebi_ids=0, pubchem_cids=1) |
| 240,310 | enrich_references | skos_definition | — | [] | Merged ChEBI/PubChem definitions into skos:definition |
| 240,311 | enrich_references | references | [] | [{"@id":"http://jglobal.jst.go.jp/en/redirect?Nikkaji_No=J36.490H","provenance":{"prov:wasGeneratedBy":"enrich_referenc… | Added references with provenance; cas_numbers=['681-84-5']; matched_chebi_ids=[]; candidate_pubchem_cids=[12682]; selected_pubchem_cids=[12682]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| 252,100 | rdkit_pre_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C4H12O4Si"… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C4H12O4Si"… | rdkit_pre_consensus from 'CO[Si](OC)(OC)OC'; added: molecular_mass, monoisotopic_mass |
| 272,481 | consensus_match | altLabel | [] | [{"@value":"CG 501","@language":"en","source":{"prov:wasGeneratedBy":"consensus_match","prov:wasAttributedTo":"brightwa… | group_key=tetramethylorthosilicate||dimension=Environmental > media=Air > strata=Aircraft cruise height; cas=681-84-5; added Common Chemistry CAS names as altLabel: CG 501, Dynasil M, Dynasylan M, KBM 04, LS 540, MKC Silicate MS 39, MZ 51, Methyl Silicate 28, Methyl Silicate 39, Methyl Silicate 40, Methyl Silicate 51L, Methyl orthosilicate, Methyl silicate, Methyl silicate ((CH<sub>3</sub>)<sub>4</sub>SiO<sub>4</sub>), Methyl silicate ((MeO)<sub>4</sub>Si), NIC-C 5, NSC 67383, OCD-T 2, SIT 7510.0, Silane, tetramethoxy-, Silicic acid (H<sub>4</sub>SiO<sub>4</sub>), tetramethyl ester, Silicon methoxide (Si(OMe)<sub>4</sub>), Silicon tetramethoxide, Siluplex, T 1980, TMOS, TO 588, TSL 8114, Tetramethoxy orthosilicate, Tetramethoxysilane, Tetramethyl silicate, WD 931; object_uuid=fo-b3c30ff19a4752b4 |
| 272,482 | consensus_match | cas_match_labels | — | {"681-84-5":"exactMatch"} | group_key=tetramethylorthosilicate||dimension=Environmental > media=Air > strata=Aircraft cruise height; group_sources=['ec_inventory', 'pubchem']; cas_sources={'681-84-5': ['ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-b3c30ff19a4752b4: {'681-84-5': 'exactMatch'} |
| 283,968 | rdkit_post_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C4H12O4Si"… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C4H12O4Si"… | rdkit_post_consensus from 'CO[Si](OC)(OC)OC'; confirmed: smiles_string, inchi2d_string, inchi2d_key_string, molecular_formula, molecular_mass, monoisotopic_mass |
| 290,111 | strip_catalogue_altlabels | altLabel | [{"@value":"CG 501","@language":"en","source":{"prov:wasGeneratedBy":"consensus_match","prov:wasAttributedTo":"brightwa… | [{"@value":"Dynasil M","@language":"en","source":{"prov:wasGeneratedBy":"consensus_match","prov:wasAttributedTo":"brigh… | Removed 9 catalogue altLabel value(s): 'CG 501' (grade code), 'KBM 04' (grade code), 'LS 540' (grade code), 'MZ 51' (grade code), 'NSC 67383' (registry code), 'T 1980' (grade code), 'TO 588' (grade code), 'TSL 8114' (grade code), 'WD 931' (grade code) |
| 305,314 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/12d28f6b-0415-… | associations resolved on the elementary layer |
| 331,370 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/557bfa3f-a386-… | associations resolved on the elementary layer |
| 333,614 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/5d3e6678-69ad-… | associations resolved on the elementary layer |
| 344,432 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/8194b3cd-4dec-… | associations resolved on the elementary layer |
| 347,867 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/8cee7527-cbe3-… | associations resolved on the elementary layer |
| 356,721 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/aab1ec9d-1919-… | associations resolved on the elementary layer |
| 357,755 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/ae1e2984-8ad1-… | associations resolved on the elementary layer |
| 359,390 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/b3eb4749-708c-… | associations resolved on the elementary layer |
| 361,969 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/bcef37b8-cd20-… | associations resolved on the elementary layer |
| 363,043 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/c0af4eee-dd21-… | associations resolved on the elementary layer |
| 378,148 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/f1bf2167-2762-… | associations resolved on the elementary layer |