2-[(methoxycarbonyl)amino]-3,3-dimethylbutanoic Acid
Everything that changed this substance, across every flow that resolves to it. Back to the substance
fo-d5c240579e46631e
Changes
56| # | Step | Field | From | To | Why |
|---|---|---|---|---|---|
| 4,705 | bootstrap_labels | prefLabel | — | [{"@value":"2-[(methoxycarbonyl)amino]-3,3-dimethylbutanoic acid","@language":"en","source":{"prov:wasGeneratedBy":"boo… | Bootstrapped prefLabel from legacy name field |
| 4,706 | bootstrap_labels | name | 2-[(methoxycarbonyl)amino]-3,3-dimethylbutanoic acid | — | Purged legacy name field to enforce prefLabel usage |
| 4,707 | bootstrap_labels | synonyms | ["organic","bms214702-01","l-tert-leucine,(n-methoxycarbonyl)-","l-valine,n-(methoxycarbonyl)-3-methyl","moc-l-tert-leu… | [] | Removed legacy synonyms field in favor of structured labels |
| 30,094 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Water","water_body":"Surface water"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to fresh water |
| 30,095 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-wate-suwa | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to fresh water |
| 43,696 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Unknown"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified |
| 43,697 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-unkn | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified |
| 47,898 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Ground","geography":"Agricultural"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to agricultural soil |
| 47,899 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-grou-agri | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to agricultural soil |
| 81,622 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","indoor":"Unknown"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, indoor |
| 81,623 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-indr-unkn | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, indoor |
| 110,782 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Water","water_body":"Ocean"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to sea water |
| 110,783 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-wate-ocea | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to sea water |
| 121,018 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Water","water_body":"Unknown"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to water, unspecified |
| 121,019 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-wate-unkn | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to water, unspecified |
| 139,074 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Long-term"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified (long-term) |
| 139,075 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-lote | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified (long-term) |
| 156,216 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Ground level","population_density":"Urban (>1000 people/square mil… | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to urban air close to ground |
| 156,217 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-grle-ur10pesq | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to urban air close to ground |
| 191,192 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Aircraft cruise height"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to lower stratosphere and upper troposphere |
| 191,193 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-aicrhe | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to lower stratosphere and upper troposphere |
| 193,982 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Medium stack, <150 meters","population_density":"Rural (<1000 peop… | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to non-urban air or from high stacks |
| 193,983 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-mest15me-ru10pesq | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to non-urban air or from high stacks |
| 195,604 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Ground","geography":"Unknown"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to soil, unspecified |
| 195,605 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-grou-unkn | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to soil, unspecified |
| 195,940 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Water","water_body":"Long-term"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to water, unspecified (long-term) |
| 195,941 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-wate-lote | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to water, unspecified (long-term) |
| 196,572 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Ground","geography":"Non-agricultural"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to non-agricultural soil |
| 196,573 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-grou-noag | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to non-agricultural soil |
| 214,911 | unit_normalization | unit_iri | — | https://vocab.brightway.one/units/unit/KiloGM | Unit IRI set from normalization of 'kg' |
| 222,175 | normalize_name_case | prefLabel | [{"@value":"2-[(methoxycarbonyl)amino]-3,3-dimethylbutanoic acid","@language":"en","source":{"prov:wasGeneratedBy":"boo… | [{"@value":"2-[(methoxycarbonyl)amino]-3,3-dimethylbutanoic Acid","@language":"en","source":{"prov:wasGeneratedBy":"boo… | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| 231,705 | enrich_references | properties | {} | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C8H15NO4"]… | Added ChEBI/PubChem properties (chebi_ids=0, pubchem_cids=1) |
| 231,706 | enrich_references | skos_definition | — | [] | Merged ChEBI/PubChem definitions into skos:definition |
| 231,707 | enrich_references | references | [] | [{"@id":"http://jglobal.jst.go.jp/en/redirect?Nikkaji_No=J1.802.444F","provenance":{"prov:wasGeneratedBy":"enrich_refer… | Added references with provenance; cas_numbers=['162537-11-3']; matched_chebi_ids=[]; candidate_pubchem_cids=[148192, 10330133, 11263950, 11469346, 16227478, 73952500]; selected_pubchem_cids=[11263950]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| 249,619 | rdkit_pre_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C8H15NO4"]… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C8H15NO4"]… | rdkit_pre_consensus from 'CC(C)(C)C(C(=O)O)NC(=O)OC'; added: inchi2d_string, molecular_mass, monoisotopic_mass |
| 260,429 | consensus_match | altLabel | [] | [{"@value":"(2S)-2-[(Methoxycarbonyl)amino]-3,3-dimethylbutanoic acid","@language":"en","source":{"prov:wasGeneratedBy"… | group_key=2-[(methoxycarbonyl)amino]-3,3-dimethylbutanoicacid||dimension=Environmental > media=Water > water_body=Surface water; cas=162537-11-3; added Common Chemistry CAS names as altLabel: (2S)-2-[(Methoxycarbonyl)amino]-3,3-dimethylbutanoic acid, (<em>S</em>)-2-(Methoxycarbonylamino)-3,3-dimethylbutanoic acid, <em>N</em>-(Methoxycarbonyl)-3-methyl-<span class="text-smallcaps">L</span>-valine, <em>N</em>-(Methoxycarbonyl)-<span class="text-smallcaps">L</span>-<em>tert</em>-leucine, <span class="text-smallcaps">L</span>-Valine, <em>N</em>-(methoxycarbonyl)-3-methyl-; object_uuid=fo-d5c240579e46631e |
| 260,430 | consensus_match | cas_match_labels | — | {"162537-11-3":"exactMatch"} | group_key=2-[(methoxycarbonyl)amino]-3,3-dimethylbutanoicacid||dimension=Environmental > media=Water > water_body=Surface water; group_sources=[]; cas_sources={'162537-11-3': []}; assigned CAS labels from group consensus; object_uuid=fo-d5c240579e46631e: {'162537-11-3': 'exactMatch'} |
| 274,748 | opsin_iupac | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C8H15NO4"]… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C8H15NO4"]… | opsin_iupac: set authoritative IUPAC name, SMILES, InChI from '(2S)-2-[(Methoxycarbonyl)amino]-3,3-dimethylbutanoic acid' |
| 281,211 | rdkit_post_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C8H15NO4"]… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C8H15NO4"]… | rdkit_post_consensus from 'COC(=O)N[C@H](C(=O)O)C(C)(C)C'; confirmed: smiles_string, inchi2d_string, inchi2d_key_string, molecular_formula, molecular_mass, monoisotopic_mass |
| 292,214 | dedupe_altlabels | altLabel | [{"@value":"(2S)-2-[(Methoxycarbonyl)amino]-3,3-dimethylbutanoic acid","@language":"en","source":{"prov:wasGeneratedBy"… | [{"@value":"(2S)-2-[(Methoxycarbonyl)amino]-3,3-dimethylbutanoic acid","@language":"en","source":{"prov:wasGeneratedBy"… | Deduplicated altLabel values and removed entries matching prefLabel |
| 296,079 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/05a11fab-3b10-… | associations resolved on the elementary layer |
| 302,867 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/0c40848c-f553-… | associations resolved on the elementary layer |
| 304,969 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/11e24250-57a8-… | associations resolved on the elementary layer |
| 321,818 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/43bdeffa-e3a6-… | associations resolved on the elementary layer |
| 336,383 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/667292db-26da-… | associations resolved on the elementary layer |
| 341,500 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/77b53fba-f0c6-… | associations resolved on the elementary layer |
| 350,531 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/964c051e-4fbe-… | associations resolved on the elementary layer |
| 359,126 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/b31bd990-1158-… | associations resolved on the elementary layer |
| 376,620 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/ec581b4b-0914-… | associations resolved on the elementary layer |
| 378,016 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/f16bcefe-891b-… | associations resolved on the elementary layer |