Picrotoxin
Everything that changed this substance, across every flow that resolves to it. Back to the substance
fo-f0a0b273231ecf65
Changes
56| # | Step | Field | From | To | Why |
|---|---|---|---|---|---|
| 15,300 | bootstrap_labels | prefLabel | — | [{"@value":"picrotoxin","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:wasAttributedTo":"con… | Bootstrapped prefLabel from legacy name field |
| 15,301 | bootstrap_labels | name | picrotoxin | — | Purged legacy name field to enforce prefLabel usage |
| 15,302 | bootstrap_labels | synonyms | ["3,6-Methano-8H-1,5,7-trioxacyclopenta(ij)cycloprop(a)azulene-4,8(3H)-dione, hexahydro-2a-hydroxy-9-(1-hydroxy-1-methy… | [] | Removed legacy synonyms field in favor of structured labels |
| 24,232 | bootstrap_labels | synonyms | ["picrotoxin","(1r,3r,5s,8s,9r,12s,13r,14r)-1-hydroxy-13-methyl-14-(prop-1-en-2-yl)-4,7,10-trioxapentacyclo[6.4.1.1â?¹,… | [] | Removed legacy synonyms field in favor of structured labels |
| 50,882 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Ground","geography":"Agricultural"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to agricultural soil |
| 50,883 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-grou-agri | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to agricultural soil |
| 67,244 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Water","water_body":"Unknown"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to water, unspecified |
| 67,245 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-wate-unkn | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to water, unspecified |
| 76,310 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Ground level","population_density":"Urban (>1000 people/square mil… | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to urban air close to ground |
| 76,311 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-grle-ur10pesq | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to urban air close to ground |
| 83,428 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Ground","geography":"Non-agricultural"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to non-agricultural soil |
| 83,429 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-grou-noag | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to non-agricultural soil |
| 99,074 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Water","water_body":"Surface water"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to fresh water |
| 99,075 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-wate-suwa | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to fresh water |
| 102,276 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Unknown"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified |
| 102,277 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-unkn | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified |
| 116,546 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Ground","geography":"Unknown"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to soil, unspecified |
| 116,547 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-grou-unkn | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to soil, unspecified |
| 118,694 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Long-term"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified (long-term) |
| 118,695 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-lote | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified (long-term) |
| 135,562 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Aircraft cruise height"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to lower stratosphere and upper troposphere |
| 135,563 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-aicrhe | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to lower stratosphere and upper troposphere |
| 141,278 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Water","water_body":"Long-term"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to water, unspecified (long-term) |
| 141,279 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-wate-lote | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to water, unspecified (long-term) |
| 148,378 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Medium stack, <150 meters","population_density":"Rural (<1000 peop… | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to non-urban air or from high stacks |
| 148,379 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-mest15me-ru10pesq | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to non-urban air or from high stacks |
| 190,312 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","indoor":"Unknown"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, indoor |
| 190,313 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-indr-unkn | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, indoor |
| 196,490 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Water","water_body":"Ocean"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to sea water |
| 196,491 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-wate-ocea | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to sea water |
| 218,375 | unit_normalization | unit_iri | — | https://vocab.brightway.one/units/unit/KiloGM | Unit IRI set from normalization of 'kg' |
| 224,617 | normalize_name_case | prefLabel | [{"@value":"picrotoxin","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:wasAttributedTo":"con… | [{"@value":"Picrotoxin","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:wasAttributedTo":"con… | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| 241,620 | enrich_references | skos_definition | — | [{"@value":"A mixture consisting of equimolar amounts of picrotoxinin and picrotin found in the climbing plant Anamirta… | Merged ChEBI/PubChem definitions into skos:definition |
| 241,621 | enrich_references | references | [] | [{"@id":"https://commonchemistry.cas.org/detail?cas_rn=124-87-8","provenance":{"prov:wasGeneratedBy":"enrich_references… | Added references with provenance; cas_numbers=['124-87-8']; matched_chebi_ids=['http://purl.obolibrary.org/obo/CHEBI_134126']; candidate_pubchem_cids=[4815, 31304, 518601, 5311359, 5458938, 6473767, 13104807, 44630180, 122130659, 124080966, 131704481, 131846146, 154731207, 169543674, 171378855, 176519983]; selected_pubchem_cids=[]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| 256,409 | chebi_altlabels | altLabel | [] | [{"@value":"(1R,3R,5S,8S,9R,12S,13R,14R)-1-hydroxy-13-methyl-14-(prop-1-en-2-yl)-4,7,10-trioxapentacyclo[6.4.1.1(9,12).… | Added 6 ChEBI synonym(s) as altLabel from 1 linked ChEBI record(s) |
| 270,747 | consensus_match | altLabel | [{"@value":"(1R,3R,5S,8S,9R,12S,13R,14R)-1-hydroxy-13-methyl-14-(prop-1-en-2-yl)-4,7,10-trioxapentacyclo[6.4.1.1(9,12).… | [{"@value":"(1R,3R,5S,8S,9R,12S,13R,14R)-1-hydroxy-13-methyl-14-(prop-1-en-2-yl)-4,7,10-trioxapentacyclo[6.4.1.1(9,12).… | group_key=picrotoxin||dimension=Environmental > media=Ground > geography=Agricultural; cas=124-87-8; added Common Chemistry CAS names as altLabel: 3,6-Methano-8<em>H</em>-1,5,7-trioxacyclopenta[<em>ij</em>]cycloprop[<em>a</em>]azulene-4,8(3<em>H</em>)-dione, hexahydro-2a-hydroxy-8b-methyl-9-(1-methylethenyl)-, (1a<em>R</em>,2a<em>R</em>,3<em>S</em>,6<em>R</em>,6a<em>S</em>,8a<em>S</em>,8b<em>R</em>,9<em>R</em>)-, compd. with (1a<em>R</em>,2a<em>R</em>,3<em>S</em>,6<em>R</em>,6a<em>S</em>,8a<em>S</em>,8b<em>R</em>,9<em>S</em>)-hexahydro-2a-hydroxy-9-(1-hydroxy-1-methylethyl)-8b-methyl-3,6-methano-8<em>H</em>-1,5,7-trioxacyclopenta[<em>ij</em>]cycloprop[<em>a</em>]azulene-4,8(3<em>H</em>)-dione (1:1), 3,6-Methano-8<em>H</em>-1,5,7-trioxacyclopenta[<em>ij</em>]cycloprop[<em>a</em>]azulene-4,8(3<em>H</em>)-dione, hexahydro-2a-hydroxy-8b-methyl-9-(1-methylethenyl)-, [1a<em>R</em>-(1aα,2aβ,3β,6β,6aβ,8a<em>S</em>*,8bβ,9<em>R</em>*)]-, compd. with [1a<em>R</em>-(1aα,2aβ,3β,6β,6aβ,8a<em>S</em>*,8bβ,9<em>S</em>*)]-hexahydro-2a-hydroxy-9-(1-hydroxy-1-methylethyl)-8b-methyl-3,6-methano-8<em>H</em>-1,5,7-trioxacyclopenta[<em>ij</em>]cycloprop[<em>a</em>]azulene-4,8(3<em>H</em>)-dione (1:1), 3,6-Methano-8<em>H</em>-1,5,7-trioxacyclopenta[<em>ij</em>]cycloprop[<em>a</em>]azulene-4,8(3<em>H</em>)-dione, hexahydro-2a-hydroxy-9-(1-hydroxy-1-methylethyl)-8b-methyl-, (1a<em>R</em>,2a<em>R</em>,3<em>S</em>,6<em>R</em>,6a<em>S</em>,8a<em>S</em>,8b<em>R</em>,9<em>S</em>)-, compd. with (1a<em>R</em>,2a<em>R</em>,3<em>S</em>,6<em>R</em>,6a<em>S</em>,8a<em>S</em>,8b<em>R</em>,9<em>R</em>)-hexahydro-2a-hydroxy-8b-methyl-9-(1-methylethenyl)-3,6-methano-8<em>H</em>-1,5,7-trioxacyclopenta[<em>ij</em>]cycloprop[<em>a</em>]azulene-4,8(3<em>H</em>)-dione (1:1), 3,6-Methano-8<em>H</em>-1,5,7-trioxacyclopenta[<em>ij</em>]cycloprop[<em>a</em>]azulene-4,8(3<em>H</em>)-dione, hexahydro-2a-hydroxy-9-(1-hydroxy-1-methylethyl)-8b-methyl-, [1a<em>R</em>-(1aα,2aβ,3β,6β,6aβ,8a<em>S</em>*,8bβ,9<em>S</em>*)]-, compd. with [1a<em>R</em>-(1aα,2aβ,3β,6β,6aβ,8a<em>S</em>*,8bβ,9<em>R</em>*)]-hexahydro-2a-hydroxy-8b-methyl-9-(1-methylethenyl)-3,6-methano-8<em>H</em>-1,5,7-trioxacyclopenta[<em>ij</em>]cycloprop[<em>a</em>]azulene-4,8(3<em>H</em>)-dione (1:1), Fish berry, MeSH ID: D010852, NSC 403139, Picrotoxinum; object_uuid=fo-f0a0b273231ecf65 |
| 270,748 | consensus_match | cas_match_labels | — | {"124-87-8":"exactMatch"} | group_key=picrotoxin||dimension=Environmental > media=Ground > geography=Agricultural; group_sources=['chebi', 'ec_inventory', 'pubchem']; cas_sources={'124-87-8': ['chebi', 'ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-f0a0b273231ecf65: {'124-87-8': 'exactMatch'} |
| 277,674 | opsin_iupac | properties | {} | {"https://w3id.org/chemrof/IUPAC_name":{"@id":"https://w3id.org/chemrof/IUPAC_name","rdfs:label":"IUPAC name","@value":… | opsin_iupac: set authoritative IUPAC name, SMILES, InChI from '3,6-Methano-8H-1,5,7-trioxacyclopenta[ij]cycloprop[a]azulene-4,8(3H)-dione, hexahydro-2a-hydroxy-8b-methyl-9-(1-methylethenyl)-, (1aR,2aR,3S,6R,6aS,8aS,8bR,9R)-, compd. with (1aR,2aR,3S,6R,6aS,8aS,8bR,9S)-hexahydro-2a-hydroxy-9-(1-hydroxy-1-methylethyl)-8b-methyl-3,6-methano-8H-1,5,7-trioxacyclopenta[ij]cycloprop[a]azulene-4,8(3H)-dione (1:1)' |
| 284,373 | rdkit_post_consensus | properties | {"https://w3id.org/chemrof/IUPAC_name":{"@id":"https://w3id.org/chemrof/IUPAC_name","rdfs:label":"IUPAC name","@value":… | {"https://w3id.org/chemrof/IUPAC_name":{"@id":"https://w3id.org/chemrof/IUPAC_name","rdfs:label":"IUPAC name","@value":… | rdkit_post_consensus from 'C=C(C)[C@@H]1[C@H]2OC(=O)[C@@H]1[C@]1(O)C[C@H]3O[C@]34C(=O)O[C@H]2[C@]14C.CC(C)(O)[C@@H]1[C@H]2OC(=O)[C@@H]1[C@]1(O)C[C@H]3O[C@]34C(=O)O[C@H]2[C@]14C'; added: inchi2d_key_string, molecular_formula, molecular_mass, monoisotopic_mass; confirmed: smiles_string, inchi2d_string |
| 290,374 | strip_catalogue_altlabels | altLabel | [{"@value":"(1R,3R,5S,8S,9R,12S,13R,14R)-1-hydroxy-13-methyl-14-(prop-1-en-2-yl)-4,7,10-trioxapentacyclo[6.4.1.1(9,12).… | [{"@value":"(1R,3R,5S,8S,9R,12S,13R,14R)-1-hydroxy-13-methyl-14-(prop-1-en-2-yl)-4,7,10-trioxapentacyclo[6.4.1.1(9,12).… | Removed 1 catalogue altLabel value(s): 'NSC 403139' (registry code) |
| 306,468 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/16ffe87d-a18a-… | associations resolved on the elementary layer |
| 314,639 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/2dd0df4a-0351-… | associations resolved on the elementary layer |
| 319,170 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/3c23e141-03d5-… | associations resolved on the elementary layer |
| 322,728 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/46d9ad44-0060-… | associations resolved on the elementary layer |
| 330,534 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/52b84a5e-664b-… | associations resolved on the elementary layer |
| 332,135 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/5858e2d6-ee30-… | associations resolved on the elementary layer |
| 339,272 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/701ff6be-2d9d-… | associations resolved on the elementary layer |
| 340,345 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/73b5570a-146b-… | associations resolved on the elementary layer |
| 348,777 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/905ed9d8-f518-… | associations resolved on the elementary layer |
| 351,640 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/9a020276-4031-… | associations resolved on the elementary layer |