Perfluorohexane
Everything that changed this flow. Back to the flow
08a91e70-3ddc-11dd-9485-0050c2490048
By field
16 fields| Field | Changes | Written by | Latest note |
|---|---|---|---|
| properties | 5 | enrich_references, normalise_property_values, opsin_iupac, rdkit_post_consensus, rdkit_pre_consensus | typed the way the ontology types it |
| altLabel | 3 | chebi_altlabels, consensus_match, strip_catalogue_altlabels | Removed 4 catalogue altLabel value(s): 'AF 0150' (grade code), 'FC 72' (grade code), 'PF 5060' (grade code), 'PP 1' (grade code) |
| prefLabel | 2 | bootstrap_labels, normalize_name_case | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| cas_match_labels | 1 | consensus_match | group_key=perfluorohexane||dimension=Environmental > media=Ground > geography=Agricultural; group_sources=['chebi', 'ec_inventory', 'pubchem']; cas_sources={'355-42-0': ['chebi', 'ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-4cfe21f6f1b5e527: {'355-42-0': 'exactMatch'} |
| context | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to non-urban air or from high stacks |
| context_iri | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to non-urban air or from high stacks |
| dcterms_is_replaced_by | 1 | pipeline.collision_decisions | merged onto a19c196e-e251-11e6-bf01-fe55135034f3 by curator ruling: EF 3.1 publishes perfluorohexane twice in this context: as `perfluorohexane` with CAS 355-42-0 and no characterisation, and as `PFC-51-14` with the climate change factor of 8620. The evidence joining them is EF 3.1's own -- the designation row carries the synonym `perfluorohexane, C6F14`, which names the substance and states its formula -- and #202 recorded the CAS on that basis. The designation row survives because it holds the factor. (#304) The compartment on this ruling was corrected from `envi-air-hist15me` to `envi-air-mest15me-ru10pesq` (#530). EF 3.1 calls one compartment `Emissions to non-urban air or from high stacks`, and the project maps that whole phrase to rural medium stack under 150 metres; the ruling had been written from the second half of EF's name instead of from the context the build assigns, so its key matched no collision and it applied to nothing. Seven rulings had the same slip, and it is what left five of the fifteen pairs in #530 sitting in one compartment. |
| ec_numbers | 1 | ec_cross_check | Resolved from EC-inventory: 206-585-0 from CAS 355-42-0 |
| is_replaced_by_uuid | 1 | pipeline.collision_decisions | merged onto a19c196e-e251-11e6-bf01-fe55135034f3 by curator ruling: EF 3.1 publishes perfluorohexane twice in this context: as `perfluorohexane` with CAS 355-42-0 and no characterisation, and as `PFC-51-14` with the climate change factor of 8620. The evidence joining them is EF 3.1's own -- the designation row carries the synonym `perfluorohexane, C6F14`, which names the substance and states its formula -- and #202 recorded the CAS on that basis. The designation row survives because it holds the factor. (#304) The compartment on this ruling was corrected from `envi-air-hist15me` to `envi-air-mest15me-ru10pesq` (#530). EF 3.1 calls one compartment `Emissions to non-urban air or from high stacks`, and the project maps that whole phrase to rural medium stack under 150 metres; the ruling had been written from the second half of EF's name instead of from the context the build assigns, so its key matched no collision and it applied to nothing. Seven rulings had the same slip, and it is what left five of the fifteen pairs in #530 sitting in one compartment. |
| name | 1 | bootstrap_labels | Purged legacy name field to enforce prefLabel usage |
| owl_deprecated | 1 | pipeline.collision_decisions | merged onto a19c196e-e251-11e6-bf01-fe55135034f3 by curator ruling: EF 3.1 publishes perfluorohexane twice in this context: as `perfluorohexane` with CAS 355-42-0 and no characterisation, and as `PFC-51-14` with the climate change factor of 8620. The evidence joining them is EF 3.1's own -- the designation row carries the synonym `perfluorohexane, C6F14`, which names the substance and states its formula -- and #202 recorded the CAS on that basis. The designation row survives because it holds the factor. (#304) The compartment on this ruling was corrected from `envi-air-hist15me` to `envi-air-mest15me-ru10pesq` (#530). EF 3.1 calls one compartment `Emissions to non-urban air or from high stacks`, and the project maps that whole phrase to rural medium stack under 150 metres; the ruling had been written from the second half of EF's name instead of from the context the build assigns, so its key matched no collision and it applied to nothing. Seven rulings had the same slip, and it is what left five of the fifteen pairs in #530 sitting in one compartment. |
| references | 1 | enrich_references | Added references with provenance; cas_numbers=['355-42-0']; matched_chebi_ids=['http://purl.obolibrary.org/obo/CHEBI_39427']; candidate_pubchem_cids=[9639]; selected_pubchem_cids=[9639]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| skos_definition | 1 | enrich_references | Merged ChEBI/PubChem definitions into skos:definition |
| synonyms | 1 | bootstrap_labels | Removed legacy synonyms field in favor of structured labels |
| types | 1 | link_flows_to_their_substance | the substance's answer, copied onto its flow |
| unit_iri | 1 | unit_normalization | Unit IRI set from normalization of 'kg' |
Where several steps wrote one field, the last one won — and the log below shows the sequence.
Changes
23| # | Step | Field | From | To | Why |
|---|---|---|---|---|---|
| 3,670 | bootstrap_labels | prefLabel | — | [{"@value":"perfluorohexane","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:wasAttributedTo"… | Bootstrapped prefLabel from legacy name field |
| 3,671 | bootstrap_labels | name | perfluorohexane | — | Purged legacy name field to enforce prefLabel usage |
| 3,672 | bootstrap_labels | synonyms | ["1,1,1,2,2,3,3,4,4,5,5,6,6,6-Tetradecafluorohexane","AC1L1THS","AF-0150","AF0150","AFO145","AFO150","Fluorinert FC72",… | [] | Removed legacy synonyms field in favor of structured labels |
| 34,304 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Medium stack, <150 meters","population_density":"Rural (<1000 peop… | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to non-urban air or from high stacks |
| 34,305 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-mest15me-ru10pesq | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to non-urban air or from high stacks |
| 214,566 | unit_normalization | unit_iri | — | https://vocab.brightway.one/units/unit/KiloGM | Unit IRI set from normalization of 'kg' |
| 221,946 | normalize_name_case | prefLabel | [{"@value":"perfluorohexane","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:wasAttributedTo"… | [{"@value":"Perfluorohexane","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:wasAttributedTo"… | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| 226,757 | ec_cross_check | ec_numbers | [] | ["206-585-0"] | Resolved from EC-inventory: 206-585-0 from CAS 355-42-0 |
| 230,716 | enrich_references | properties | {} | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6F14"],"a… | Added ChEBI/PubChem properties (chebi_ids=1, pubchem_cids=1) |
| 230,717 | enrich_references | skos_definition | — | [{"@value":"A fluoroalkane that is hexane in which all of the hydrogens have been replaced by fluorines.","@language":"… | Merged ChEBI/PubChem definitions into skos:definition |
| 230,718 | enrich_references | references | [] | [{"@id":"beilstein:1802113","provenance":{"prov:wasGeneratedBy":"enrich_references.chebi_xrefs","prov:wasAttributedTo":… | Added references with provenance; cas_numbers=['355-42-0']; matched_chebi_ids=['http://purl.obolibrary.org/obo/CHEBI_39427']; candidate_pubchem_cids=[9639]; selected_pubchem_cids=[9639]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| 249,338 | rdkit_pre_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6F14"],"a… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6F14"],"a… | rdkit_pre_consensus from 'C(C(C(C(F)(F)F)(F)F)(F)F)(C(C(F)(F)F)(F)F)(F)F'; added: monoisotopic_mass |
| 254,850 | chebi_altlabels | altLabel | [] | [{"@value":"1,1,1,2,2,3,3,4,4,5,5,6,6,6-tetradecafluorohexane","@language":"en","source":{"prov:wasGeneratedBy":"chebi_… | Added 5 ChEBI synonym(s) as altLabel from 1 linked ChEBI record(s) |
| 270,518 | consensus_match | altLabel | [{"@value":"1,1,1,2,2,3,3,4,4,5,5,6,6,6-tetradecafluorohexane","@language":"en","source":{"prov:wasGeneratedBy":"chebi_… | [{"@value":"1,1,1,2,2,3,3,4,4,5,5,6,6,6-tetradecafluorohexane","@language":"en","source":{"prov:wasGeneratedBy":"chebi_… | group_key=perfluorohexane||dimension=Environmental > media=Ground > geography=Agricultural; cas=355-42-0; added Common Chemistry CAS names as altLabel: AF 0150, FC 72, Fluorinert FC 72, Fluorinert FX 3250D, Fluorinert PF 5060, Flutec PP 1, Hexane, 1,1,1,2,2,3,3,4,4,5,5,6,6,6-tetradecafluoro-, Hexane, tetradecafluoro-, PF 5060, PFC 51-14, PP 1, Perfluoro-<em>n</em>-hexane; object_uuid=fo-4cfe21f6f1b5e527 |
| 270,520 | consensus_match | cas_match_labels | — | {"355-42-0":"exactMatch"} | group_key=perfluorohexane||dimension=Environmental > media=Ground > geography=Agricultural; group_sources=['chebi', 'ec_inventory', 'pubchem']; cas_sources={'355-42-0': ['chebi', 'ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-4cfe21f6f1b5e527: {'355-42-0': 'exactMatch'} |
| 274,468 | opsin_iupac | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6F14"],"a… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6F14"],"a… | opsin_iupac: set authoritative IUPAC name, SMILES, InChI from 'Perfluorohexane' |
| 280,908 | rdkit_post_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6F14"],"a… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6F14"],"a… | rdkit_post_consensus from 'FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F'; confirmed: smiles_string, inchi2d_string, inchi2d_key_string, molecular_formula, molecular_mass, monoisotopic_mass |
| 288,012 | strip_catalogue_altlabels | altLabel | [{"@value":"1,1,1,2,2,3,3,4,4,5,5,6,6,6-tetradecafluorohexane","@language":"en","source":{"prov:wasGeneratedBy":"chebi_… | [{"@value":"1,1,1,2,2,3,3,4,4,5,5,6,6,6-tetradecafluorohexane","@language":"en","source":{"prov:wasGeneratedBy":"chebi_… | Removed 4 catalogue altLabel value(s): 'AF 0150' (grade code), 'FC 72' (grade code), 'PF 5060' (grade code), 'PP 1' (grade code) |
| 293,264 | pipeline.collision_decisions | owl_deprecated | — | yes | merged onto a19c196e-e251-11e6-bf01-fe55135034f3 by curator ruling: EF 3.1 publishes perfluorohexane twice in this context: as `perfluorohexane` with CAS 355-42-0 and no characterisation, and as `PFC-51-14` with the climate change factor of 8620. The evidence joining them is EF 3.1's own -- the designation row carries the synonym `perfluorohexane, C6F14`, which names the substance and states its formula -- and #202 recorded the CAS on that basis. The designation row survives because it holds the factor. (#304) The compartment on this ruling was corrected from `envi-air-hist15me` to `envi-air-mest15me-ru10pesq` (#530). EF 3.1 calls one compartment `Emissions to non-urban air or from high stacks`, and the project maps that whole phrase to rural medium stack under 150 metres; the ruling had been written from the second half of EF's name instead of from the context the build assigns, so its key matched no collision and it applied to nothing. Seven rulings had the same slip, and it is what left five of the fifteen pairs in #530 sitting in one compartment. |
| 293,265 | pipeline.collision_decisions | dcterms_is_replaced_by | — | urn:uuid:a19c196e-e251-11e6-bf01-fe55135034f3 | merged onto a19c196e-e251-11e6-bf01-fe55135034f3 by curator ruling: EF 3.1 publishes perfluorohexane twice in this context: as `perfluorohexane` with CAS 355-42-0 and no characterisation, and as `PFC-51-14` with the climate change factor of 8620. The evidence joining them is EF 3.1's own -- the designation row carries the synonym `perfluorohexane, C6F14`, which names the substance and states its formula -- and #202 recorded the CAS on that basis. The designation row survives because it holds the factor. (#304) The compartment on this ruling was corrected from `envi-air-hist15me` to `envi-air-mest15me-ru10pesq` (#530). EF 3.1 calls one compartment `Emissions to non-urban air or from high stacks`, and the project maps that whole phrase to rural medium stack under 150 metres; the ruling had been written from the second half of EF's name instead of from the context the build assigns, so its key matched no collision and it applied to nothing. Seven rulings had the same slip, and it is what left five of the fifteen pairs in #530 sitting in one compartment. |
| 293,266 | pipeline.collision_decisions | is_replaced_by_uuid | — | a19c196e-e251-11e6-bf01-fe55135034f3 | merged onto a19c196e-e251-11e6-bf01-fe55135034f3 by curator ruling: EF 3.1 publishes perfluorohexane twice in this context: as `perfluorohexane` with CAS 355-42-0 and no characterisation, and as `PFC-51-14` with the climate change factor of 8620. The evidence joining them is EF 3.1's own -- the designation row carries the synonym `perfluorohexane, C6F14`, which names the substance and states its formula -- and #202 recorded the CAS on that basis. The designation row survives because it holds the factor. (#304) The compartment on this ruling was corrected from `envi-air-hist15me` to `envi-air-mest15me-ru10pesq` (#530). EF 3.1 calls one compartment `Emissions to non-urban air or from high stacks`, and the project maps that whole phrase to rural medium stack under 150 metres; the ruling had been written from the second half of EF's name instead of from the context the build assigns, so its key matched no collision and it applied to nothing. Seven rulings had the same slip, and it is what left five of the fifteen pairs in #530 sitting in one compartment. |
| 388,765 | normalise_property_values | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6F14"],"a… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6F14"],"a… | typed the way the ontology types it |
| 395,640 | link_flows_to_their_substance | types | — | ["https://w3id.org/chemrof/NeutralMolecule"] | the substance's answer, copied onto its flow |
PROV-O trail
23 activitiesOne activity per change: which version of the flow it consumed, and which it produced. The values are on the change with the same number — stored once, not twice.
| Activity | Field | Agent | Used | Generated |
|---|---|---|---|---|
| ef:activity/change/20260822T0600486828500000/3670 | prefLabel | ef:agent/bootstrap_labels | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v0 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v1 |
| ef:activity/change/20260822T0600486828500000/3671 | name | ef:agent/bootstrap_labels | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v1 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v2 |
| ef:activity/change/20260822T0600486828500000/3672 | synonyms | ef:agent/bootstrap_labels | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v2 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v3 |
| ef:activity/change/20260822T0600486828500000/34304 | context | ef:agent/default_context_mapping | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v3 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v4 |
| ef:activity/change/20260822T0600486828500000/34305 | context_iri | ef:agent/default_context_mapping | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v4 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v5 |
| ef:activity/change/20260822T0600486828500000/214566 | unit_iri | ef:agent/unit_normalization | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v5 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v6 |
| ef:activity/change/20260822T0600486828500000/221946 | prefLabel | ef:agent/normalize_name_case | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v6 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v7 |
| ef:activity/change/20260822T0600486828500000/226757 | ec_numbers | ef:agent/ec_cross_check | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v7 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v8 |
| ef:activity/change/20260822T0600486828500000/230716 | properties | ef:agent/enrich_references | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v8 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v9 |
| ef:activity/change/20260822T0600486828500000/230717 | skos_definition | ef:agent/enrich_references | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v9 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v10 |
| ef:activity/change/20260822T0600486828500000/230718 | references | ef:agent/enrich_references | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v10 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v11 |
| ef:activity/change/20260822T0600486828500000/249338 | properties | ef:agent/rdkit_pre_consensus | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v11 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v12 |
| ef:activity/change/20260822T0600486828500000/254850 | altLabel | ef:agent/chebi_altlabels | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v12 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v13 |
| ef:activity/change/20260822T0600486828500000/270518 | altLabel | ef:agent/consensus_match | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v13 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v14 |
| ef:activity/change/20260822T0600486828500000/270520 | cas_match_labels | ef:agent/consensus_match | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v14 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v15 |
| ef:activity/change/20260822T0600486828500000/274468 | properties | ef:agent/opsin_iupac | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v15 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v16 |
| ef:activity/change/20260822T0600486828500000/280908 | properties | ef:agent/rdkit_post_consensus | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v16 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v17 |
| ef:activity/change/20260822T0600486828500000/288012 | altLabel | ef:agent/strip_catalogue_altlabels | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v17 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v18 |
| ef:activity/change/20260822T0600486828500000/293264 | owl_deprecated | ef:agent/pipeline.collision_decisions | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v18 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v19 |
| ef:activity/change/20260822T0600486828500000/293265 | dcterms_is_replaced_by | ef:agent/pipeline.collision_decisions | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v19 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v20 |
| ef:activity/change/20260822T0600486828500000/293266 | is_replaced_by_uuid | ef:agent/pipeline.collision_decisions | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v20 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v21 |
| ef:activity/change/20260822T0600486828500000/388765 | properties | ef:agent/normalise_property_values | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v21 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v22 |
| ef:activity/change/20260822T0600486828500000/395640 | types | ef:agent/link_flows_to_their_substance | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v22 | ef:flow/08a91e70-3ddc-11dd-9485-0050c2490048/v23 |