Pyrazophos
Everything that changed this flow. Back to the flow
08a91e70-3ddc-11dd-9eea-0050c2490048
By field
14 fields| Field | Changes | Written by | Latest note |
|---|---|---|---|
| properties | 5 | enrich_references, normalise_property_values, opsin_iupac, rdkit_post_consensus, rdkit_pre_consensus | typed the way the ontology types it |
| altLabel | 3 | chebi_altlabels, consensus_match, strip_catalogue_altlabels | Removed 3 catalogue altLabel value(s): 'HOE 2873' (grade code), 'Hoechst 2873' (trade name), 'NSC 232671' (registry code) |
| prefLabel | 2 | bootstrap_labels, normalize_name_case | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| cas_match_labels | 1 | consensus_match | group_key=pyrazophos||dimension=Environmental > media=Ground > geography=Agricultural; group_sources=['chebi', 'ec_inventory', 'pubchem']; cas_sources={'13457-18-6': ['chebi', 'ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-68a7e2bea7b4909e: {'13457-18-6': 'exactMatch'} |
| concept_associations | 1 | carry_associations_onto_flows | associations resolved on the elementary layer |
| context | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified |
| context_iri | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified |
| name | 1 | bootstrap_labels | Purged legacy name field to enforce prefLabel usage |
| references | 1 | enrich_references | Added references with provenance; cas_numbers=['13457-18-6']; matched_chebi_ids=['http://purl.obolibrary.org/obo/CHEBI_81942']; candidate_pubchem_cids=[26033]; selected_pubchem_cids=[26033]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| roles | 1 | link_flows_to_their_substance | the substance's answer, copied onto its flow |
| skos_definition | 1 | enrich_references | Merged ChEBI/PubChem definitions into skos:definition |
| synonyms | 1 | bootstrap_labels | Removed legacy synonyms field in favor of structured labels |
| types | 1 | link_flows_to_their_substance | the substance's answer, copied onto its flow |
| unit_iri | 1 | unit_normalization | Unit IRI set from normalization of 'kg' |
Where several steps wrote one field, the last one won — and the log below shows the sequence.
Changes
21| # | Step | Field | From | To | Why |
|---|---|---|---|---|---|
| 8,728 | bootstrap_labels | prefLabel | — | [{"@value":"pyrazophos","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:wasAttributedTo":"con… | Bootstrapped prefLabel from legacy name field |
| 8,729 | bootstrap_labels | name | pyrazophos | — | Purged legacy name field to enforce prefLabel usage |
| 8,730 | bootstrap_labels | synonyms | ["2-(Diethoxy-thiophosphoryloxy)-5-methyl-pyrazolo[1,5-a]pyrimidine-6-carboxylic acid ethyl ester","2-(O,O-Diethyl thio… | [] | Removed legacy synonyms field in favor of structured labels |
| 39,516 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Unknown"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified |
| 39,517 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-unkn | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified |
| 216,249 | unit_normalization | unit_iri | — | https://vocab.brightway.one/units/unit/KiloGM | Unit IRI set from normalization of 'kg' |
| 223,161 | normalize_name_case | prefLabel | [{"@value":"pyrazophos","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:wasAttributedTo":"con… | [{"@value":"Pyrazophos","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:wasAttributedTo":"con… | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| 235,532 | enrich_references | properties | {} | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C14H20N3O5… | Added ChEBI/PubChem properties (chebi_ids=1, pubchem_cids=1) |
| 235,533 | enrich_references | skos_definition | — | [{"@value":"A member of the class of pyrazolopyrimidines that is the ethyl ester of 2-[(diethoxyphosphorothioyl)oxy]-5-… | Merged ChEBI/PubChem definitions into skos:definition |
| 235,534 | enrich_references | references | [] | [{"@id":"agr:IND83071499","provenance":{"prov:wasGeneratedBy":"enrich_references.chebi_xrefs","prov:wasAttributedTo":"c… | Added references with provenance; cas_numbers=['13457-18-6']; matched_chebi_ids=['http://purl.obolibrary.org/obo/CHEBI_81942']; candidate_pubchem_cids=[26033]; selected_pubchem_cids=[26033]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| 250,724 | rdkit_pre_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C14H20N3O5… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C14H20N3O5… | rdkit_pre_consensus from 'CCOC(=O)C1=CN2C(=CC(=N2)OP(=S)(OCC)OCC)N=C1C'; added: monoisotopic_mass |
| 255,624 | chebi_altlabels | altLabel | [] | [{"@value":"2-(O,O-Diethylthionophosphoryl)-5-methyl-6-carbethoxy-pyrazolo-(1,5a)pyrimidine","@language":"en","source":… | Added 5 ChEBI synonym(s) as altLabel from 1 linked ChEBI record(s) |
| 271,202 | consensus_match | altLabel | [{"@value":"2-(O,O-Diethylthionophosphoryl)-5-methyl-6-carbethoxy-pyrazolo-(1,5a)pyrimidine","@language":"en","source":… | [{"@value":"2-(O,O-Diethylthionophosphoryl)-5-methyl-6-carbethoxy-pyrazolo-(1,5a)pyrimidine","@language":"en","source":… | group_key=pyrazophos||dimension=Environmental > media=Ground > geography=Agricultural; cas=13457-18-6; added Common Chemistry CAS names as altLabel: 2-(<em>O</em>,<em>O</em>-Diethylthionophosphoryl)-5-methyl-6-carbethoxypyrazolopyrimidine, Afugan, Afugan WP 30, Curamil, Diethyl 6-carbethoxy-5-methylpyrazolo[1,5-<em>a</em>]pyrimidin-2-yl phosphorothioate, HOE 2873, Hoechst 2873, Missile, NSC 232671, Pyrazolo[1,5-<em>a</em>]pyrimidine-6-carboxylic acid, 2-[(diethoxyphosphinothioyl)oxy]-5-methyl-, ethyl ester, Pyrazolo[1,5-<em>a</em>]pyrimidine-6-carboxylic acid, 2-hydroxy-5-methyl-, ethyl ester, <em>O</em>-ester with <em>O</em>,<em>O</em>-diethyl phosphorothioate; object_uuid=fo-68a7e2bea7b4909e |
| 271,203 | consensus_match | cas_match_labels | — | {"13457-18-6":"exactMatch"} | group_key=pyrazophos||dimension=Environmental > media=Ground > geography=Agricultural; group_sources=['chebi', 'ec_inventory', 'pubchem']; cas_sources={'13457-18-6': ['chebi', 'ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-68a7e2bea7b4909e: {'13457-18-6': 'exactMatch'} |
| 275,905 | opsin_iupac | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C14H20N3O5… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C14H20N3O5… | opsin_iupac: set authoritative IUPAC name, SMILES, InChI from 'Ethyl 2-((diethoxyphosphinothioyl)oxy)-5-methylpyrazolo(1,5-a)pyrimidine-6-carboxylate' |
| 282,472 | rdkit_post_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C14H20N3O5… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C14H20N3O5… | rdkit_post_consensus from 'CCOC(=O)c1cn2nc(OP(=S)(OCC)OCC)cc2nc1C'; confirmed: smiles_string, inchi2d_string, inchi2d_key_string, molecular_formula, molecular_mass, monoisotopic_mass |
| 289,087 | strip_catalogue_altlabels | altLabel | [{"@value":"2-(O,O-Diethylthionophosphoryl)-5-methyl-6-carbethoxy-pyrazolo-(1,5a)pyrimidine","@language":"en","source":… | [{"@value":"2-(O,O-Diethylthionophosphoryl)-5-methyl-6-carbethoxy-pyrazolo-(1,5a)pyrimidine","@language":"en","source":… | Removed 3 catalogue altLabel value(s): 'HOE 2873' (grade code), 'Hoechst 2873' (trade name), 'NSC 232671' (registry code) |
| 300,803 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/08a91e70-3ddc-… | associations resolved on the elementary layer |
| 390,254 | normalise_property_values | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C14H20N3O5… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C14H20N3O5… | typed the way the ontology types it |
| 397,782 | link_flows_to_their_substance | types | — | ["https://w3id.org/chemrof/NeutralMolecule"] | the substance's answer, copied onto its flow |
| 397,783 | link_flows_to_their_substance | roles | — | [{"@id":"http://purl.obolibrary.org/obo/CHEBI_33286","rdfs:label":"agrochemical","http://www.w3.org/2004/02/skos/core#d… | the substance's answer, copied onto its flow |
PROV-O trail
21 activitiesOne activity per change: which version of the flow it consumed, and which it produced. The values are on the change with the same number — stored once, not twice.
| Activity | Field | Agent | Used | Generated |
|---|---|---|---|---|
| ef:activity/change/20260820T1416470405690000/8728 | prefLabel | ef:agent/bootstrap_labels | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v0 | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v1 |
| ef:activity/change/20260820T1416470405690000/8729 | name | ef:agent/bootstrap_labels | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v1 | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v2 |
| ef:activity/change/20260820T1416470405690000/8730 | synonyms | ef:agent/bootstrap_labels | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v2 | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v3 |
| ef:activity/change/20260820T1416470405690000/39516 | context | ef:agent/default_context_mapping | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v3 | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v4 |
| ef:activity/change/20260820T1416470405690000/39517 | context_iri | ef:agent/default_context_mapping | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v4 | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v5 |
| ef:activity/change/20260820T1416470405690000/216249 | unit_iri | ef:agent/unit_normalization | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v5 | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v6 |
| ef:activity/change/20260820T1416470405690000/223161 | prefLabel | ef:agent/normalize_name_case | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v6 | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v7 |
| ef:activity/change/20260820T1416470405690000/235532 | properties | ef:agent/enrich_references | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v7 | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v8 |
| ef:activity/change/20260820T1416470405690000/235533 | skos_definition | ef:agent/enrich_references | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v8 | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v9 |
| ef:activity/change/20260820T1416470405690000/235534 | references | ef:agent/enrich_references | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v9 | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v10 |
| ef:activity/change/20260820T1416470405690000/250724 | properties | ef:agent/rdkit_pre_consensus | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v10 | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v11 |
| ef:activity/change/20260820T1416470405690000/255624 | altLabel | ef:agent/chebi_altlabels | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v11 | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v12 |
| ef:activity/change/20260820T1416470405690000/271202 | altLabel | ef:agent/consensus_match | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v12 | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v13 |
| ef:activity/change/20260820T1416470405690000/271203 | cas_match_labels | ef:agent/consensus_match | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v13 | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v14 |
| ef:activity/change/20260820T1416470405690000/275905 | properties | ef:agent/opsin_iupac | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v14 | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v15 |
| ef:activity/change/20260820T1416470405690000/282472 | properties | ef:agent/rdkit_post_consensus | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v15 | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v16 |
| ef:activity/change/20260820T1416470405690000/289087 | altLabel | ef:agent/strip_catalogue_altlabels | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v16 | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v17 |
| ef:activity/change/20260820T1416470405690000/300803 | concept_associations | ef:agent/carry_associations_onto_flows | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v17 | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v18 |
| ef:activity/change/20260820T1416470405690000/390254 | properties | ef:agent/normalise_property_values | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v18 | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v19 |
| ef:activity/change/20260820T1416470405690000/397782 | types | ef:agent/link_flows_to_their_substance | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v19 | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v20 |
| ef:activity/change/20260820T1416470405690000/397783 | roles | ef:agent/link_flows_to_their_substance | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v20 | ef:flow/08a91e70-3ddc-11dd-9eea-0050c2490048/v21 |