Reaction Mass Of 1,3-bis[2-(terbutylperoxy)propan-2-yl]benzene And 1,4-bis[2-(terbutylperoxy)propan-2-yl]benzene
Everything that changed this flow. Back to the flow
10b69c6c-d565-4dc2-b880-97240e4ce2f8
By field
13 fields| Field | Changes | Written by | Latest note |
|---|---|---|---|
| properties | 4 | enrich_references, rdkit_post_consensus, rdkit_pre_consensus, withhold_ambiguous_mass | withhold_ambiguous_mass: removed molecular_mass, monoisotopic_mass; the flow carries 3 candidate structures, so no one mass describes it |
| altLabel | 3 | consensus_match, strip_catalogue_altlabels, strip_product_families | Removed 31 product-family altLabel value(s) from 3 famil(y/ies): 'luperox' (13, e.g. 'Luperox 802PP40'), 'perkadox' (13, e.g. 'Perkadox 14'), 'varox' (5, e.g. 'Varox 802-402KE') |
| prefLabel | 2 | bootstrap_labels, normalize_name_case | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| cas_match_labels | 1 | consensus_match | group_key=reactionmassof1,3-bis[2-(terbutylperoxy)propan-2-yl]benzeneand1,4-bis[2-(terbutylperoxy)propan-2-yl]benzene||dimension=Environmental > media=Ground > geography=Agricultural; group_sources=['ec_inventory']; cas_sources={'25155-25-3': ['ec_inventory']}; assigned CAS labels from group consensus; object_uuid=fo-196fe2a66cc1e8fc: {'25155-25-3': 'exactMatch'} |
| concept_associations | 1 | carry_associations_onto_flows | associations resolved on the elementary layer |
| context | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to agricultural soil |
| context_iri | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to agricultural soil |
| name | 1 | bootstrap_labels | Purged legacy name field to enforce prefLabel usage |
| references | 1 | enrich_references | Added references with provenance; cas_numbers=['25155-25-3']; matched_chebi_ids=[]; candidate_pubchem_cids=[16654, 17721, 11856263, 53400407]; selected_pubchem_cids=[17721, 11856263, 53400407]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| skos_definition | 1 | enrich_references | Merged ChEBI/PubChem definitions into skos:definition |
| synonyms | 1 | bootstrap_labels | Removed legacy synonyms field in favor of structured labels |
| types | 1 | link_flows_to_their_substance | the substance's answer, copied onto its flow |
| unit_iri | 1 | unit_normalization | Unit IRI set from normalization of 'kg' |
Where several steps wrote one field, the last one won — and the log below shows the sequence.
Changes
19| # | Step | Field | From | To | Why |
|---|---|---|---|---|---|
| 13,078 | bootstrap_labels | prefLabel | — | [{"@value":"reaction mass of 1,3-bis[2-(terbutylperoxy)propan-2-yl]benzene and 1,4-bis[2-(terbutylperoxy)propan-2-yl]be… | Bootstrapped prefLabel from legacy name field |
| 13,079 | bootstrap_labels | name | reaction mass of 1,3-bis[2-(terbutylperoxy)propan-2-yl]benzene and 1,4-bis[2-(terbutylperoxy)propan-2-yl]benzene | — | Purged legacy name field to enforce prefLabel usage |
| 13,080 | bootstrap_labels | synonyms | ["organic","[1,3(or1,4)-phenylenebis(1-methylethylidene)]bis[tert-butyl]peroxide","faridabipb","perkadox14","perkadox14… | [] | Removed legacy synonyms field in favor of structured labels |
| 47,236 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Ground","geography":"Agricultural"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to agricultural soil |
| 47,237 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-grou-agri | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to agricultural soil |
| 217,663 | unit_normalization | unit_iri | — | https://vocab.brightway.one/units/unit/KiloGM | Unit IRI set from normalization of 'kg' |
| 224,122 | normalize_name_case | prefLabel | [{"@value":"reaction mass of 1,3-bis[2-(terbutylperoxy)propan-2-yl]benzene and 1,4-bis[2-(terbutylperoxy)propan-2-yl]be… | [{"@value":"Reaction Mass Of 1,3-bis[2-(terbutylperoxy)propan-2-yl]benzene And 1,4-bis[2-(terbutylperoxy)propan-2-yl]be… | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| 239,587 | enrich_references | properties | {} | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C20H34O4"]… | Added ChEBI/PubChem properties (chebi_ids=0, pubchem_cids=3) |
| 239,588 | enrich_references | skos_definition | — | [] | Merged ChEBI/PubChem definitions into skos:definition |
| 239,589 | enrich_references | references | [] | [{"@id":"http://jglobal.jst.go.jp/en/redirect?Nikkaji_No=J155.570G","provenance":{"prov:wasGeneratedBy":"enrich_referen… | Added references with provenance; cas_numbers=['25155-25-3']; matched_chebi_ids=[]; candidate_pubchem_cids=[16654, 17721, 11856263, 53400407]; selected_pubchem_cids=[17721, 11856263, 53400407]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| 251,885 | rdkit_pre_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C20H34O4"]… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C20H34O4"]… | rdkit_pre_consensus from 'CC(C)(C)C(C(C)(C1=CC=CC=C1C(C)(C(C(C)(C)C)O)O)O)O'; added: molecular_mass, monoisotopic_mass |
| 271,313 | consensus_match | altLabel | [] | [{"@value":"1,1′-[1,3(<em>or</em> 1,4)-Phenylenebis(1-methylethylidene)]bis[2-(1,1-dimethylethyl) peroxide]","@language… | group_key=reactionmassof1,3-bis[2-(terbutylperoxy)propan-2-yl]benzeneand1,4-bis[2-(terbutylperoxy)propan-2-yl]benzene||dimension=Environmental > media=Ground > geography=Agricultural; cas=25155-25-3; added Common Chemistry CAS names as altLabel: 1,1′-[1,3(<em>or</em> 1,4)-Phenylenebis(1-methylethylidene)]bis[2-(1,1-dimethylethyl) peroxide], 1,3(4)-Bis(<em>tert</em>-butylperoxyisopropyl)benzene, 1,3(4)-Bis[1-(<em>tert</em>-butylperoxy)-1-methylethyl]benzene, 14-40B, 14S-FL, 2,2′-Bis(<em>tert</em>-butylperoxy)diisopropylbenzene, 96BIBP, ACEOX BIBP, Antioxidant 14-40B, BIBP, BIPB 40B, BP 40, BPIB, Bis(2-<em>tert</em>-butylperoxyisopropyl)benzene, Bis(<em>tert</em>-butyldioxy)diisopropylbenzene, Bis(<em>tert</em>-butyldioxyisopropyl)benzene, Bis(<em>tert</em>-butylperoxy)diisopropylbenzene, Bis(<em>tert</em>-butylperoxyisopropyl)benzene, Bis[1-(<em>tert</em>-butyldioxy)-1-methylethyl]benzene, Bis[α-(<em>tert</em>-butylperoxy)isopropyl]benzene, CS 5101, Di(2-<em>t</em>-butylperoxyisopropyl)benzene, Di(<em>tert</em>-butylperoxyisopropyl)benzene, Di-<em>tert</em>-butylperoxy diisopropylbenzene, E(VC)D 40, F 40ED, F 40P, F 40P-SP2, F 80, F 80 (peroxide), F Flakes, Farida BIPB 40A, Interox DIPP 40IC/G, KF-B 50CC, Luperco 802-40KE, Luperox 802, Luperox 802PP40, Luperox F, Luperox F 40, Luperox F 40ED, Luperox F 40KEP, Luperox F 40M-SP, Luperox F 40MF, Luperox F 40MG, Luperox F 40P, Luperox F 40P-SP, Luperox F 40P-SP2, Luperox F 40S, Luperox F 40T-SP, Luperox F 90P, Luperox F Flakes, Luperox F-CST, Novoperoks BP 40, Novoperox PB 40, P 14, PBP 98, PX 14SFL, Perbutyl P 40MB, Perbutyl PT, Perhexa F 40, Perkadox 14, Perkadox 14-40B, Perkadox 14-40B-GR, Perkadox 14-40B-PD, Perkadox 14-40BD, Perkadox 14-40K-PD, Perkadox 14-40MB, Perkadox 14/40MB-GR, Perkadox 1440, Perkadox 14R, Perkadox 14RP, Perkadox 14S, Perkadox 14S-FL, Perkadox 14SFI, Peroxan BIB, Peroxan BIB 40EV-G, Peroxan BIB 40P, Peroxan BIB 40PE-G, Peroxide, (phenylenediisopropylidene)bis[<em>tert</em>-butyl, Peroxide, 1,1′-[1,3(<em>or</em> 1,4)-phenylenebis(1-methylethylidene)]bis[2-(1,1-dimethylethyl), Peroxide, [1,3(<em>or</em> 1,4)-phenylenebis(1-methylethylidene)]bis[(1,1-dimethylethyl), Peroximon F, Peroximon F 40, Peroximon F 40KEP, Peroximon F 40MG, Peroximon F 40SRG, Peroximon PK, Polydispersion T-VC-D 40P, Polyvel CR 5P, Px 14, Retilox F, Rhenocure VC 40CC, Trigonox 265-50B, VC 40, VC 40CC, VC 40K, Varox 802-402KE, Varox 802-40C-SP2, Varox 802-40CST, Varox 802-40KE, Varox 802-40SP, Varox VC-R, Vul-Cup, Vul-Cup 40KE, Vul-Cup 40SI, Vul-Cup KD 60, Vul-Cup R, Vul-cup 40C, α,α<sup>,</sup>-Di(<em>tert</em>-butylperoxy)diisopropylbenzene, α,α′-Bis(<em>tert</em>-butylperoxy)diisopropylbenzene, α,α′-Di(<em>tert</em>-butylperoxy)diisopropylbenzene, α,α′-Di(<em>tert</em>-butylperoxyisopropyl)benzene, α′,α′-Bis(<em>tert</em>-butylperoxy)diisopropylbenzene; object_uuid=fo-196fe2a66cc1e8fc |
| 271,314 | consensus_match | cas_match_labels | — | {"25155-25-3":"exactMatch"} | group_key=reactionmassof1,3-bis[2-(terbutylperoxy)propan-2-yl]benzeneand1,4-bis[2-(terbutylperoxy)propan-2-yl]benzene||dimension=Environmental > media=Ground > geography=Agricultural; group_sources=['ec_inventory']; cas_sources={'25155-25-3': ['ec_inventory']}; assigned CAS labels from group consensus; object_uuid=fo-196fe2a66cc1e8fc: {'25155-25-3': 'exactMatch'} |
| 283,734 | rdkit_post_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C20H34O4"]… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C20H34O4"]… | rdkit_post_consensus from 'CC(C)(C)C(C(C)(C1=CC=CC=C1C(C)(C(C(C)(C)C)O)O)O)O'; confirmed: smiles_string, inchi2d_string, inchi2d_key_string, molecular_formula, molecular_mass, monoisotopic_mass |
| 287,011 | withhold_ambiguous_mass | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C20H34O4"]… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C20H34O4"]… | withhold_ambiguous_mass: removed molecular_mass, monoisotopic_mass; the flow carries 3 candidate structures, so no one mass describes it |
| 289,940 | strip_catalogue_altlabels | altLabel | [{"@value":"1,1′-[1,3(<em>or</em> 1,4)-Phenylenebis(1-methylethylidene)]bis[2-(1,1-dimethylethyl) peroxide]","@language… | [{"@value":"1,1′-[1,3(or 1,4)-Phenylenebis(1-methylethylidene)]bis[2-(1,1-dimethylethyl) peroxide]","@language":"en","s… | Removed 13 catalogue altLabel value(s): 'BIPB 40B' (grade code), 'BP 40' (grade code), 'CS 5101' (grade code), 'F 40P' (grade code), 'F 80' (grade code), 'F 80 (peroxide)' (grade code), 'Luperox 802' (trade name), 'P 14' (grade code), 'PBP 98' (grade code), 'Perkadox 1440' (trade name), 'Px 14' (grade code), 'VC 40' (grade code), 'VC 40K' (grade code) |
| 291,903 | strip_product_families | altLabel | [{"@value":"1,1′-[1,3(or 1,4)-Phenylenebis(1-methylethylidene)]bis[2-(1,1-dimethylethyl) peroxide]","@language":"en","s… | [{"@value":"1,1′-[1,3(or 1,4)-Phenylenebis(1-methylethylidene)]bis[2-(1,1-dimethylethyl) peroxide]","@language":"en","s… | Removed 31 product-family altLabel value(s) from 3 famil(y/ies): 'luperox' (13, e.g. 'Luperox 802PP40'), 'perkadox' (13, e.g. 'Perkadox 14'), 'varox' (5, e.g. 'Varox 802-402KE') |
| 304,645 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/10b69c6c-d565-… | associations resolved on the elementary layer |
| 399,456 | link_flows_to_their_substance | types | — | ["https://w3id.org/chemrof/NeutralMolecule"] | the substance's answer, copied onto its flow |
PROV-O trail
19 activitiesOne activity per change: which version of the flow it consumed, and which it produced. The values are on the change with the same number — stored once, not twice.
| Activity | Field | Agent | Used | Generated |
|---|---|---|---|---|
| ef:activity/change/20260821T1554374006150000/13078 | prefLabel | ef:agent/bootstrap_labels | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v0 | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v1 |
| ef:activity/change/20260821T1554374006150000/13079 | name | ef:agent/bootstrap_labels | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v1 | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v2 |
| ef:activity/change/20260821T1554374006150000/13080 | synonyms | ef:agent/bootstrap_labels | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v2 | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v3 |
| ef:activity/change/20260821T1554374006150000/47236 | context | ef:agent/default_context_mapping | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v3 | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v4 |
| ef:activity/change/20260821T1554374006150000/47237 | context_iri | ef:agent/default_context_mapping | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v4 | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v5 |
| ef:activity/change/20260821T1554374006150000/217663 | unit_iri | ef:agent/unit_normalization | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v5 | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v6 |
| ef:activity/change/20260821T1554374006150000/224122 | prefLabel | ef:agent/normalize_name_case | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v6 | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v7 |
| ef:activity/change/20260821T1554374006150000/239587 | properties | ef:agent/enrich_references | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v7 | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v8 |
| ef:activity/change/20260821T1554374006150000/239588 | skos_definition | ef:agent/enrich_references | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v8 | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v9 |
| ef:activity/change/20260821T1554374006150000/239589 | references | ef:agent/enrich_references | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v9 | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v10 |
| ef:activity/change/20260821T1554374006150000/251885 | properties | ef:agent/rdkit_pre_consensus | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v10 | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v11 |
| ef:activity/change/20260821T1554374006150000/271313 | altLabel | ef:agent/consensus_match | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v11 | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v12 |
| ef:activity/change/20260821T1554374006150000/271314 | cas_match_labels | ef:agent/consensus_match | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v12 | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v13 |
| ef:activity/change/20260821T1554374006150000/283734 | properties | ef:agent/rdkit_post_consensus | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v13 | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v14 |
| ef:activity/change/20260821T1554374006150000/287011 | properties | ef:agent/withhold_ambiguous_mass | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v14 | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v15 |
| ef:activity/change/20260821T1554374006150000/289940 | altLabel | ef:agent/strip_catalogue_altlabels | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v15 | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v16 |
| ef:activity/change/20260821T1554374006150000/291903 | altLabel | ef:agent/strip_product_families | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v16 | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v17 |
| ef:activity/change/20260821T1554374006150000/304645 | concept_associations | ef:agent/carry_associations_onto_flows | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v17 | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v18 |
| ef:activity/change/20260821T1554374006150000/399456 | types | ef:agent/link_flows_to_their_substance | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v18 | ef:flow/10b69c6c-d565-4dc2-b880-97240e4ce2f8/v19 |