Bis[oxidovanadium(2+)] Diphosphate
Everything that changed this flow. Back to the flow
1550c975-a784-448b-b983-d26c6e164cf9
By field
13 fields| Field | Changes | Written by | Latest note |
|---|---|---|---|
| properties | 5 | enrich_references, opsin_iupac, rdkit_post_consensus, rdkit_pre_consensus, withhold_ambiguous_mass | withhold_ambiguous_mass: removed molecular_mass, monoisotopic_mass; the flow carries 2 candidate structures, so no one mass describes it |
| altLabel | 2 | consensus_match, dedupe_altlabels | Deduplicated altLabel values and removed entries matching prefLabel |
| prefLabel | 2 | bootstrap_labels, normalize_name_case | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| cas_match_labels | 1 | consensus_match | group_key=bis[oxidovanadium(2+)]diphosphate||dimension=Environmental > media=Air > strata=Long-term; group_sources=[]; cas_sources={'58834-75-6': []}; assigned CAS labels from group consensus; object_uuid=fo-f060d4d509a87423: {'58834-75-6': 'exactMatch'} |
| concept_associations | 1 | carry_associations_onto_flows | associations resolved on the elementary layer |
| context | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified (long-term) |
| context_iri | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified (long-term) |
| name | 1 | bootstrap_labels | Purged legacy name field to enforce prefLabel usage |
| references | 1 | enrich_references | Added references with provenance; cas_numbers=['58834-75-6']; matched_chebi_ids=[]; candidate_pubchem_cids=[86278579, 138394571]; selected_pubchem_cids=[86278579, 138394571]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| skos_definition | 1 | enrich_references | Merged ChEBI/PubChem definitions into skos:definition |
| synonyms | 1 | bootstrap_labels | Removed legacy synonyms field in favor of structured labels |
| types | 1 | link_flows_to_their_substance | the substance's answer, copied onto its flow |
| unit_iri | 1 | unit_normalization | Unit IRI set from normalization of 'kg' |
Where several steps wrote one field, the last one won — and the log below shows the sequence.
Changes
19| # | Step | Field | From | To | Why |
|---|---|---|---|---|---|
| 14,792 | bootstrap_labels | prefLabel | — | [{"@value":"bis[oxidovanadium(2+)] diphosphate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","pr… | Bootstrapped prefLabel from legacy name field |
| 14,793 | bootstrap_labels | name | bis[oxidovanadium(2+)] diphosphate | — | Purged legacy name field to enforce prefLabel usage |
| 14,794 | bootstrap_labels | synonyms | ["inorganic","vanadylpyrophosphate","mancatalystfv100","polycat-almabtnexhausted","polycat-almax","polycat-almax4","pol… | [] | Removed legacy synonyms field in favor of structured labels |
| 49,957 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Long-term"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified (long-term) |
| 49,958 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-lote | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified (long-term) |
| 218,219 | unit_normalization | unit_iri | — | https://vocab.brightway.one/units/unit/KiloGM | Unit IRI set from normalization of 'kg' |
| 224,509 | normalize_name_case | prefLabel | [{"@value":"bis[oxidovanadium(2+)] diphosphate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","pr… | [{"@value":"Bis[oxidovanadium(2+)] Diphosphate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","pr… | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| 241,177 | enrich_references | properties | {} | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["H4O9P2V2"]… | Added ChEBI/PubChem properties (chebi_ids=0, pubchem_cids=2) |
| 241,178 | enrich_references | skos_definition | — | [] | Merged ChEBI/PubChem definitions into skos:definition |
| 241,179 | enrich_references | references | [] | [{"@id":"https://commonchemistry.cas.org/detail?cas_rn=58834-75-6","provenance":{"prov:wasGeneratedBy":"enrich_referenc… | Added references with provenance; cas_numbers=['58834-75-6']; matched_chebi_ids=[]; candidate_pubchem_cids=[86278579, 138394571]; selected_pubchem_cids=[86278579, 138394571]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| 252,353 | rdkit_pre_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["H4O9P2V2"]… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["H4O9P2V2"]… | rdkit_pre_consensus from 'OP(=O)(O)OP(=O)(O)O.O=[V].O=[V]'; added: molecular_mass, monoisotopic_mass |
| 264,411 | consensus_match | altLabel | [] | [{"@value":"Diphosphoric acid, vanadium complex","@language":"en","source":{"prov:wasGeneratedBy":"consensus_match","pr… | group_key=bis[oxidovanadium(2+)]diphosphate||dimension=Environmental > media=Air > strata=Long-term; cas=58834-75-6; added Common Chemistry CAS names as altLabel: Diphosphoric acid, vanadium complex, Divanadyl diphosphate, Divanadyl pyrophosphate, Vanadium oxide phosphate [(VO)<sub>2</sub>(P<sub>2</sub>O<sub>7</sub>)], Vanadium oxide pyrophosphate (V<sub>2</sub>O<sub>2</sub>(P<sub>2</sub>O<sub>7</sub>)), Vanadium, [diphosphato(4-)]dioxodi-, Vanadium, [μ-[diphosphato(4-)-<em>O</em>,<em>O</em>′′:<em>O</em>′,<em>O</em>′′′]]dioxodi-, Vanadium, [μ-[diphosphato(4-)-κ<em>O</em>,κ<em>O</em>′′:κ<em>O</em>′,κ<em>O</em>′′′]]dioxodi-, Vanadyl diphosphate, Vanadyl diphosphate [(VO)<sub>2</sub>(P<sub>2</sub>O<sub>7</sub>)], Vanadyl phosphate (V<sub>2</sub>O<sub>2</sub>P<sub>2</sub>O<sub>7</sub>), Vanadyl pyrophosphate, Vanadyl pyrophosphate ((VO)<sub>2</sub>P<sub>2</sub>O<sub>7</sub>), [μ-[Diphosphato(4-)-κ<em>O</em>,κ<em>O</em>′′:κ<em>O</em>′,κ<em>O</em>′′′]]dioxodivanadium; object_uuid=fo-f060d4d509a87423 |
| 264,412 | consensus_match | cas_match_labels | — | {"58834-75-6":"exactMatch"} | group_key=bis[oxidovanadium(2+)]diphosphate||dimension=Environmental > media=Air > strata=Long-term; group_sources=[]; cas_sources={'58834-75-6': []}; assigned CAS labels from group consensus; object_uuid=fo-f060d4d509a87423: {'58834-75-6': 'exactMatch'} |
| 277,547 | opsin_iupac | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["H4O9P2V2"]… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["H4O9P2V2"]… | opsin_iupac: set authoritative IUPAC name, SMILES, InChI from 'Bis[oxidovanadium(2+)] Diphosphate' |
| 284,242 | rdkit_post_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["H4O9P2V2"]… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["H4O9P2V2",… | rdkit_post_consensus from 'O=P([O-])([O-])OP(=O)([O-])[O-].[O]=[V+2].[O]=[V+2]'; added: inchi2d_key_string, molecular_formula, molecular_mass, monoisotopic_mass; confirmed: smiles_string, inchi2d_string |
| 287,063 | withhold_ambiguous_mass | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["H4O9P2V2",… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["H4O9P2V2",… | withhold_ambiguous_mass: removed molecular_mass, monoisotopic_mass; the flow carries 2 candidate structures, so no one mass describes it |
| 292,795 | dedupe_altlabels | altLabel | [{"@value":"Diphosphoric acid, vanadium complex","@language":"en","source":{"prov:wasGeneratedBy":"consensus_match","pr… | [{"@value":"Diphosphoric acid, vanadium complex","@language":"en","source":{"prov:wasGeneratedBy":"consensus_match","pr… | Deduplicated altLabel values and removed entries matching prefLabel |
| 306,046 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/1550c975-a784-… | associations resolved on the elementary layer |
| 400,163 | link_flows_to_their_substance | types | — | ["https://w3id.org/chemrof/ChemicalSalt"] | the substance's answer, copied onto its flow |
PROV-O trail
19 activitiesOne activity per change: which version of the flow it consumed, and which it produced. The values are on the change with the same number — stored once, not twice.
| Activity | Field | Agent | Used | Generated |
|---|---|---|---|---|
| ef:activity/change/20261019T0712047113160000/14792 | prefLabel | ef:agent/bootstrap_labels | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v0 | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v1 |
| ef:activity/change/20261019T0712047113160000/14793 | name | ef:agent/bootstrap_labels | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v1 | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v2 |
| ef:activity/change/20261019T0712047113160000/14794 | synonyms | ef:agent/bootstrap_labels | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v2 | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v3 |
| ef:activity/change/20261019T0712047113160000/49957 | context | ef:agent/default_context_mapping | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v3 | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v4 |
| ef:activity/change/20261019T0712047113160000/49958 | context_iri | ef:agent/default_context_mapping | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v4 | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v5 |
| ef:activity/change/20261019T0712047113160000/218219 | unit_iri | ef:agent/unit_normalization | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v5 | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v6 |
| ef:activity/change/20261019T0712047113160000/224509 | prefLabel | ef:agent/normalize_name_case | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v6 | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v7 |
| ef:activity/change/20261019T0712047113160000/241177 | properties | ef:agent/enrich_references | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v7 | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v8 |
| ef:activity/change/20261019T0712047113160000/241178 | skos_definition | ef:agent/enrich_references | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v8 | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v9 |
| ef:activity/change/20261019T0712047113160000/241179 | references | ef:agent/enrich_references | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v9 | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v10 |
| ef:activity/change/20261019T0712047113160000/252353 | properties | ef:agent/rdkit_pre_consensus | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v10 | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v11 |
| ef:activity/change/20261019T0712047113160000/264411 | altLabel | ef:agent/consensus_match | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v11 | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v12 |
| ef:activity/change/20261019T0712047113160000/264412 | cas_match_labels | ef:agent/consensus_match | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v12 | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v13 |
| ef:activity/change/20261019T0712047113160000/277547 | properties | ef:agent/opsin_iupac | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v13 | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v14 |
| ef:activity/change/20261019T0712047113160000/284242 | properties | ef:agent/rdkit_post_consensus | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v14 | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v15 |
| ef:activity/change/20261019T0712047113160000/287063 | properties | ef:agent/withhold_ambiguous_mass | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v15 | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v16 |
| ef:activity/change/20261019T0712047113160000/292795 | altLabel | ef:agent/dedupe_altlabels | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v16 | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v17 |
| ef:activity/change/20261019T0712047113160000/306046 | concept_associations | ef:agent/carry_associations_onto_flows | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v17 | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v18 |
| ef:activity/change/20261019T0712047113160000/400163 | types | ef:agent/link_flows_to_their_substance | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v18 | ef:flow/1550c975-a784-448b-b983-d26c6e164cf9/v19 |