Tetrapropyl Orthosilicate
Everything that changed this flow. Back to the flow
22a3bf87-53f1-4a8f-96f9-e6104fbc4380
By field
13 fields| Field | Changes | Written by | Latest note |
|---|---|---|---|
| properties | 5 | enrich_references, normalise_property_values, opsin_iupac, rdkit_post_consensus, rdkit_pre_consensus | typed the way the ontology types it |
| altLabel | 2 | consensus_match, dedupe_altlabels | Deduplicated altLabel values and removed entries matching prefLabel |
| prefLabel | 2 | bootstrap_labels, normalize_name_case | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| cas_match_labels | 1 | consensus_match | group_key=tetrapropylorthosilicate||dimension=Environmental > media=Air > strata=Long-term; group_sources=['ec_inventory', 'pubchem']; cas_sources={'682-01-9': ['ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-ee6db5fffd43386e: {'682-01-9': 'exactMatch'} |
| concept_associations | 1 | carry_associations_onto_flows | associations resolved on the elementary layer |
| context | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to sea water |
| context_iri | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to sea water |
| name | 1 | bootstrap_labels | Purged legacy name field to enforce prefLabel usage |
| references | 1 | enrich_references | Added references with provenance; cas_numbers=['682-01-9']; matched_chebi_ids=[]; candidate_pubchem_cids=[69590, 69627]; selected_pubchem_cids=[69627]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| skos_definition | 1 | enrich_references | Merged ChEBI/PubChem definitions into skos:definition |
| synonyms | 1 | bootstrap_labels | Removed legacy synonyms field in favor of structured labels |
| types | 1 | link_flows_to_their_substance | the substance's answer, copied onto its flow |
| unit_iri | 1 | unit_normalization | Unit IRI set from normalization of 'kg' |
Where several steps wrote one field, the last one won — and the log below shows the sequence.
Changes
19| # | Step | Field | From | To | Why |
|---|---|---|---|---|---|
| 4,542 | bootstrap_labels | prefLabel | — | [{"@value":"tetrapropyl orthosilicate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:wasAtt… | Bootstrapped prefLabel from legacy name field |
| 4,543 | bootstrap_labels | name | tetrapropyl orthosilicate | — | Purged legacy name field to enforce prefLabel usage |
| 4,544 | bootstrap_labels | synonyms | ["organometallic","tetrapropylorthosilicate","dynasilp","dynasylan(r)p","y-15673"] | [] | Removed legacy synonyms field in favor of structured labels |
| 59,692 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Water","water_body":"Ocean"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to sea water |
| 59,693 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-wate-ocea | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to sea water |
| 214,856 | unit_normalization | unit_iri | — | https://vocab.brightway.one/units/unit/KiloGM | Unit IRI set from normalization of 'kg' |
| 222,136 | normalize_name_case | prefLabel | [{"@value":"tetrapropyl orthosilicate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:wasAtt… | [{"@value":"Tetrapropyl Orthosilicate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:wasAtt… | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| 231,548 | enrich_references | properties | {} | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C12H28O4Si… | Added ChEBI/PubChem properties (chebi_ids=0, pubchem_cids=1) |
| 231,549 | enrich_references | skos_definition | — | [] | Merged ChEBI/PubChem definitions into skos:definition |
| 231,550 | enrich_references | references | [] | [{"@id":"http://jglobal.jst.go.jp/en/redirect?Nikkaji_No=J113.278D","provenance":{"prov:wasGeneratedBy":"enrich_referen… | Added references with provenance; cas_numbers=['682-01-9']; matched_chebi_ids=[]; candidate_pubchem_cids=[69590, 69627]; selected_pubchem_cids=[69627]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| 249,572 | rdkit_pre_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C12H28O4Si… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C12H28O4Si… | rdkit_pre_consensus from 'CCCO[Si](OCCC)(OCCC)OCCC'; added: molecular_mass, monoisotopic_mass |
| 272,503 | consensus_match | altLabel | [] | [{"@value":"Dynasil P","@language":"en","source":{"prov:wasGeneratedBy":"consensus_match","prov:wasAttributedTo":"conse… | group_key=tetrapropylorthosilicate||dimension=Environmental > media=Air > strata=Long-term; cas=682-01-9; added Common Chemistry CAS names as altLabel: Dynasil P, Dynasylan P, N-POS, Propyl orthosilicate, Propyl silicate, Propyl silicate ((PrO)<sub>4</sub>Si), SIT 7777.0, Silane, tetrapropoxy-, Silicic acid (H<sub>4</sub>SiO<sub>4</sub>), tetrapropyl ester, Silicon orthopropoxide, Silicon tetrapropoxide, Tetra-<em>n</em>-propoxysilane, Tetra-<em>n</em>-propyl orthosilicate, Tetra-<em>n</em>-propyl silicate, Tetrapropoxy orthosilicate, Tetrapropoxysilane, Tetrapropyl silicate; object_uuid=fo-ee6db5fffd43386e |
| 272,504 | consensus_match | cas_match_labels | — | {"682-01-9":"exactMatch"} | group_key=tetrapropylorthosilicate||dimension=Environmental > media=Air > strata=Long-term; group_sources=['ec_inventory', 'pubchem']; cas_sources={'682-01-9': ['ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-ee6db5fffd43386e: {'682-01-9': 'exactMatch'} |
| 274,705 | opsin_iupac | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C12H28O4Si… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C12H28O4Si… | opsin_iupac: set authoritative IUPAC name, SMILES, InChI from 'Tetrapropyl Orthosilicate' |
| 281,167 | rdkit_post_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C12H28O4Si… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C12H28O4Si… | rdkit_post_consensus from 'CCCO[Si](OCCC)(OCCC)OCCC'; confirmed: smiles_string, inchi2d_string, inchi2d_key_string, molecular_formula, molecular_mass, monoisotopic_mass |
| 292,209 | dedupe_altlabels | altLabel | [{"@value":"Dynasil P","@language":"en","source":{"prov:wasGeneratedBy":"consensus_match","prov:wasAttributedTo":"conse… | [{"@value":"Dynasil P","@language":"en","source":{"prov:wasGeneratedBy":"consensus_match","prov:wasAttributedTo":"conse… | Deduplicated altLabel values and removed entries matching prefLabel |
| 310,865 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/22a3bf87-53f1-… | associations resolved on the elementary layer |
| 389,013 | normalise_property_values | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C12H28O4Si… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C12H28O4Si… | typed the way the ontology types it |
| 395,983 | link_flows_to_their_substance | types | — | ["https://w3id.org/chemrof/NeutralMolecule"] | the substance's answer, copied onto its flow |
PROV-O trail
19 activitiesOne activity per change: which version of the flow it consumed, and which it produced. The values are on the change with the same number — stored once, not twice.
| Activity | Field | Agent | Used | Generated |
|---|---|---|---|---|
| ef:activity/change/20260821T1302361922970000/4542 | prefLabel | ef:agent/bootstrap_labels | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v0 | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v1 |
| ef:activity/change/20260821T1302361922970000/4543 | name | ef:agent/bootstrap_labels | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v1 | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v2 |
| ef:activity/change/20260821T1302361922970000/4544 | synonyms | ef:agent/bootstrap_labels | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v2 | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v3 |
| ef:activity/change/20260821T1302361922970000/59692 | context | ef:agent/default_context_mapping | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v3 | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v4 |
| ef:activity/change/20260821T1302361922970000/59693 | context_iri | ef:agent/default_context_mapping | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v4 | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v5 |
| ef:activity/change/20260821T1302361922970000/214856 | unit_iri | ef:agent/unit_normalization | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v5 | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v6 |
| ef:activity/change/20260821T1302361922970000/222136 | prefLabel | ef:agent/normalize_name_case | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v6 | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v7 |
| ef:activity/change/20260821T1302361922970000/231548 | properties | ef:agent/enrich_references | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v7 | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v8 |
| ef:activity/change/20260821T1302361922970000/231549 | skos_definition | ef:agent/enrich_references | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v8 | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v9 |
| ef:activity/change/20260821T1302361922970000/231550 | references | ef:agent/enrich_references | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v9 | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v10 |
| ef:activity/change/20260821T1302361922970000/249572 | properties | ef:agent/rdkit_pre_consensus | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v10 | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v11 |
| ef:activity/change/20260821T1302361922970000/272503 | altLabel | ef:agent/consensus_match | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v11 | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v12 |
| ef:activity/change/20260821T1302361922970000/272504 | cas_match_labels | ef:agent/consensus_match | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v12 | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v13 |
| ef:activity/change/20260821T1302361922970000/274705 | properties | ef:agent/opsin_iupac | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v13 | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v14 |
| ef:activity/change/20260821T1302361922970000/281167 | properties | ef:agent/rdkit_post_consensus | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v14 | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v15 |
| ef:activity/change/20260821T1302361922970000/292209 | altLabel | ef:agent/dedupe_altlabels | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v15 | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v16 |
| ef:activity/change/20260821T1302361922970000/310865 | concept_associations | ef:agent/carry_associations_onto_flows | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v16 | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v17 |
| ef:activity/change/20260821T1302361922970000/389013 | properties | ef:agent/normalise_property_values | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v17 | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v18 |
| ef:activity/change/20260821T1302361922970000/395983 | types | ef:agent/link_flows_to_their_substance | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v18 | ef:flow/22a3bf87-53f1-4a8f-96f9-e6104fbc4380/v19 |