Tert-butyl 2-methylpropaneperoxoate
Everything that changed this flow. Back to the flow
23038374-2c27-41f3-84ff-9890b0dea789
By field
13 fields| Field | Changes | Written by | Latest note |
|---|---|---|---|
| properties | 5 | enrich_references, normalise_property_values, opsin_iupac, rdkit_post_consensus, rdkit_pre_consensus | typed the way the ontology types it |
| altLabel | 2 | consensus_match, dedupe_altlabels | Deduplicated altLabel values and removed entries matching prefLabel |
| prefLabel | 2 | bootstrap_labels, normalize_name_case | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| cas_match_labels | 1 | consensus_match | group_key=tert-butyl2-methylpropaneperoxoate||dimension=Environmental > media=Ground > geography=Unknown; group_sources=['ec_inventory', 'pubchem']; cas_sources={'109-13-7': ['ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-2d70930d7f8f8ac8: {'109-13-7': 'exactMatch'} |
| concept_associations | 1 | carry_associations_onto_flows | associations resolved on the elementary layer |
| context | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to soil, unspecified |
| context_iri | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to soil, unspecified |
| name | 1 | bootstrap_labels | Purged legacy name field to enforce prefLabel usage |
| references | 1 | enrich_references | Added references with provenance; cas_numbers=['109-13-7']; matched_chebi_ids=[]; candidate_pubchem_cids=[61023, 53446645]; selected_pubchem_cids=[61023]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| skos_definition | 1 | enrich_references | Merged ChEBI/PubChem definitions into skos:definition |
| synonyms | 1 | bootstrap_labels | Removed legacy synonyms field in favor of structured labels |
| types | 1 | link_flows_to_their_substance | the substance's answer, copied onto its flow |
| unit_iri | 1 | unit_normalization | Unit IRI set from normalization of 'kg' |
Where several steps wrote one field, the last one won — and the log below shows the sequence.
Changes
19| # | Step | Field | From | To | Why |
|---|---|---|---|---|---|
| 18,655 | bootstrap_labels | prefLabel | — | [{"@value":"tert-butyl 2-methylpropaneperoxoate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","p… | Bootstrapped prefLabel from legacy name field |
| 18,656 | bootstrap_labels | name | tert-butyl 2-methylpropaneperoxoate | — | Purged legacy name field to enforce prefLabel usage |
| 18,657 | bootstrap_labels | synonyms | ["organic","tert-butylperoxyisobutyrate"] | [] | Removed legacy synonyms field in favor of structured labels |
| 59,912 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Ground","geography":"Unknown"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to soil, unspecified |
| 59,913 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-grou-unkn | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to soil, unspecified |
| 219,431 | unit_normalization | unit_iri | — | https://vocab.brightway.one/units/unit/KiloGM | Unit IRI set from normalization of 'kg' |
| 225,337 | normalize_name_case | prefLabel | [{"@value":"tert-butyl 2-methylpropaneperoxoate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","p… | [{"@value":"Tert-butyl 2-methylpropaneperoxoate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","p… | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| 244,588 | enrich_references | properties | {} | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C8H16O3"],… | Added ChEBI/PubChem properties (chebi_ids=0, pubchem_cids=1) |
| 244,589 | enrich_references | skos_definition | — | [] | Merged ChEBI/PubChem definitions into skos:definition |
| 244,590 | enrich_references | references | [] | [{"@id":"http://jglobal.jst.go.jp/en/redirect?Nikkaji_No=J2.431G","provenance":{"prov:wasGeneratedBy":"enrich_reference… | Added references with provenance; cas_numbers=['109-13-7']; matched_chebi_ids=[]; candidate_pubchem_cids=[61023, 53446645]; selected_pubchem_cids=[61023]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| 253,336 | rdkit_pre_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C8H16O3"],… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C8H16O3"],… | rdkit_pre_consensus from 'CC(C)C(=O)OOC(C)(C)C'; added: molecular_mass, monoisotopic_mass |
| 272,312 | consensus_match | altLabel | [] | [{"@value":"<em>tert</em>-Butyl perisobutyrate","@language":"en","source":{"prov:wasGeneratedBy":"consensus_match","pro… | group_key=tert-butyl2-methylpropaneperoxoate||dimension=Environmental > media=Ground > geography=Unknown; cas=109-13-7; added Common Chemistry CAS names as altLabel: <em>tert</em>-Butyl perisobutyrate, <em>tert</em>-Butyl peroxyisobutyrate, Chemex IB, Esperox 24M, Kayaester I, LQ-TBPI, Lupersol 8, Lupersol 80, Perbutyl IB, Peroxyisobutyric acid, <em>tert</em>-butyl ester, Propaneperoxoic acid, 2-methyl-, 1,1-dimethylethyl ester, Trigonox 41C75, t-Butyl peroxyisobutyrate; object_uuid=fo-2d70930d7f8f8ac8 |
| 272,313 | consensus_match | cas_match_labels | — | {"109-13-7":"exactMatch"} | group_key=tert-butyl2-methylpropaneperoxoate||dimension=Environmental > media=Ground > geography=Unknown; group_sources=['ec_inventory', 'pubchem']; cas_sources={'109-13-7': ['ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-2d70930d7f8f8ac8: {'109-13-7': 'exactMatch'} |
| 278,547 | opsin_iupac | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C8H16O3"],… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C8H16O3"],… | opsin_iupac: set authoritative IUPAC name, SMILES, InChI from 'Tert-butyl 2-methylpropaneperoxoate' |
| 285,317 | rdkit_post_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C8H16O3"],… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C8H16O3"],… | rdkit_post_consensus from 'CC(C)C(=O)OOC(C)(C)C'; confirmed: smiles_string, inchi2d_string, inchi2d_key_string, molecular_formula, molecular_mass, monoisotopic_mass |
| 293,004 | dedupe_altlabels | altLabel | [{"@value":"<em>tert</em>-Butyl perisobutyrate","@language":"en","source":{"prov:wasGeneratedBy":"consensus_match","pro… | [{"@value":"tert-Butyl perisobutyrate","@language":"en","source":{"prov:wasGeneratedBy":"consensus_match","prov:wasAttr… | Deduplicated altLabel values and removed entries matching prefLabel |
| 310,975 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/23038374-2c27-… | associations resolved on the elementary layer |
| 392,914 | normalise_property_values | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C8H16O3"],… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C8H16O3"],… | typed the way the ontology types it |
| 401,611 | link_flows_to_their_substance | types | — | ["https://w3id.org/chemrof/NeutralMolecule"] | the substance's answer, copied onto its flow |
PROV-O trail
19 activitiesOne activity per change: which version of the flow it consumed, and which it produced. The values are on the change with the same number — stored once, not twice.
| Activity | Field | Agent | Used | Generated |
|---|---|---|---|---|
| ef:activity/change/20260821T1302361922970000/18655 | prefLabel | ef:agent/bootstrap_labels | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v0 | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v1 |
| ef:activity/change/20260821T1302361922970000/18656 | name | ef:agent/bootstrap_labels | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v1 | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v2 |
| ef:activity/change/20260821T1302361922970000/18657 | synonyms | ef:agent/bootstrap_labels | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v2 | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v3 |
| ef:activity/change/20260821T1302361922970000/59912 | context | ef:agent/default_context_mapping | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v3 | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v4 |
| ef:activity/change/20260821T1302361922970000/59913 | context_iri | ef:agent/default_context_mapping | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v4 | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v5 |
| ef:activity/change/20260821T1302361922970000/219431 | unit_iri | ef:agent/unit_normalization | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v5 | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v6 |
| ef:activity/change/20260821T1302361922970000/225337 | prefLabel | ef:agent/normalize_name_case | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v6 | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v7 |
| ef:activity/change/20260821T1302361922970000/244588 | properties | ef:agent/enrich_references | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v7 | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v8 |
| ef:activity/change/20260821T1302361922970000/244589 | skos_definition | ef:agent/enrich_references | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v8 | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v9 |
| ef:activity/change/20260821T1302361922970000/244590 | references | ef:agent/enrich_references | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v9 | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v10 |
| ef:activity/change/20260821T1302361922970000/253336 | properties | ef:agent/rdkit_pre_consensus | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v10 | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v11 |
| ef:activity/change/20260821T1302361922970000/272312 | altLabel | ef:agent/consensus_match | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v11 | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v12 |
| ef:activity/change/20260821T1302361922970000/272313 | cas_match_labels | ef:agent/consensus_match | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v12 | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v13 |
| ef:activity/change/20260821T1302361922970000/278547 | properties | ef:agent/opsin_iupac | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v13 | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v14 |
| ef:activity/change/20260821T1302361922970000/285317 | properties | ef:agent/rdkit_post_consensus | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v14 | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v15 |
| ef:activity/change/20260821T1302361922970000/293004 | altLabel | ef:agent/dedupe_altlabels | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v15 | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v16 |
| ef:activity/change/20260821T1302361922970000/310975 | concept_associations | ef:agent/carry_associations_onto_flows | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v16 | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v17 |
| ef:activity/change/20260821T1302361922970000/392914 | properties | ef:agent/normalise_property_values | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v17 | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v18 |
| ef:activity/change/20260821T1302361922970000/401611 | types | ef:agent/link_flows_to_their_substance | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v18 | ef:flow/23038374-2c27-41f3-84ff-9890b0dea789/v19 |