Diisopropyl fluorophosphate
Everything that changed this flow. Back to the flow
4031cd4c-d8ba-4f6a-8653-13147d1b3728
By field
13 fields| Field | Changes | Written by | Latest note |
|---|---|---|---|
| properties | 5 | enrich_references, normalise_property_values, opsin_iupac, rdkit_post_consensus, rdkit_pre_consensus | typed the way the ontology types it |
| altLabel | 4 | chebi_altlabels, consensus_match, dedupe_altlabels | Deduplicated altLabel values and removed entries matching prefLabel |
| prefLabel | 3 | bootstrap_labels, consensus_match, normalize_name_case | cas=55-91-4; cc_chebi_agreed_name='Diisopropyl fluorophosphate'; object_uuid=fo-55f3a83cada29fea |
| cas_match_labels | 1 | consensus_match | group_key=diisopropylphosphorofluoridate||dimension=Environmental > media=Air > strata=Long-term; group_sources=['chebi', 'ec_inventory', 'pubchem']; cas_sources={'55-91-4': ['chebi', 'ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-55f3a83cada29fea: {'55-91-4': 'exactMatch'} |
| concept_associations | 1 | carry_associations_onto_flows | associations resolved on the elementary layer |
| context | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, indoor |
| context_iri | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, indoor |
| name | 1 | bootstrap_labels | Purged legacy name field to enforce prefLabel usage |
| references | 1 | enrich_references | Added references with provenance; cas_numbers=['55-91-4']; matched_chebi_ids=['http://purl.obolibrary.org/obo/CHEBI_17941']; candidate_pubchem_cids=[5936, 24203253]; selected_pubchem_cids=[5936]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| skos_definition | 1 | enrich_references | Merged ChEBI/PubChem definitions into skos:definition |
| synonyms | 1 | bootstrap_labels | Removed legacy synonyms field in favor of structured labels |
| types | 1 | link_flows_to_their_substance | the substance's answer, copied onto its flow |
| unit_iri | 1 | unit_normalization | Unit IRI set from normalization of 'kg' |
Where several steps wrote one field, the last one won — and the log below shows the sequence.
Changes
22| # | Step | Field | From | To | Why |
|---|---|---|---|---|---|
| 12,608 | bootstrap_labels | prefLabel | — | [{"@value":"diisopropyl phosphorofluoridate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:… | Bootstrapped prefLabel from legacy name field |
| 12,609 | bootstrap_labels | name | diisopropyl phosphorofluoridate | — | Purged legacy name field to enforce prefLabel usage |
| 17,124 | bootstrap_labels | synonyms | ["diisopropylphosphorofluoridate","bis(propan-2-yl)fluorophosphonate","2-[fluoro(propan-2-yloxy)phosphoryl]oxypropane",… | [] | Removed legacy synonyms field in favor of structured labels |
| 79,676 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","indoor":"Unknown"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, indoor |
| 79,677 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-indr-unkn | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, indoor |
| 217,511 | unit_normalization | unit_iri | — | https://vocab.brightway.one/units/unit/KiloGM | Unit IRI set from normalization of 'kg' |
| 224,019 | normalize_name_case | prefLabel | [{"@value":"diisopropyl phosphorofluoridate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:… | [{"@value":"Diisopropyl Phosphorofluoridate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:… | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| 239,158 | enrich_references | properties | {} | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6H14FO3P"… | Added ChEBI/PubChem properties (chebi_ids=1, pubchem_cids=1) |
| 239,159 | enrich_references | skos_definition | — | [] | Merged ChEBI/PubChem definitions into skos:definition |
| 239,160 | enrich_references | references | [] | [{"@id":"drugcentral:1494","provenance":{"prov:wasGeneratedBy":"enrich_references.chebi_xrefs","prov:wasAttributedTo":"… | Added references with provenance; cas_numbers=['55-91-4']; matched_chebi_ids=['http://purl.obolibrary.org/obo/CHEBI_17941']; candidate_pubchem_cids=[5936, 24203253]; selected_pubchem_cids=[5936]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| 251,761 | rdkit_pre_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6H14FO3P"… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6H14FO3P"… | rdkit_pre_consensus from 'CC(C)OP(=O)(F)OC(C)C'; added: monoisotopic_mass |
| 256,113 | chebi_altlabels | altLabel | [] | [{"@value":"DFP","@language":"en","source":{"prov:wasGeneratedBy":"chebi_altlabels","prov:wasAttributedTo":"consensus-f… | Added 18 ChEBI synonym(s) as altLabel from 1 linked ChEBI record(s) |
| 266,018 | consensus_match | prefLabel | [{"@value":"Diisopropyl Phosphorofluoridate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:… | [{"@value":"Diisopropyl fluorophosphate","@language":"en","source":{"prov:wasGeneratedBy":"consensus_match","prov:wasAt… | cas=55-91-4; cc_chebi_agreed_name='Diisopropyl fluorophosphate'; object_uuid=fo-55f3a83cada29fea |
| 266,019 | consensus_match | altLabel | [{"@value":"DFP","@language":"en","source":{"prov:wasGeneratedBy":"chebi_altlabels","prov:wasAttributedTo":"consensus-f… | [{"@value":"DFP","@language":"en","source":{"prov:wasGeneratedBy":"chebi_altlabels","prov:wasAttributedTo":"consensus-f… | cas=55-91-4; added original name as altLabel after CC/ChEBI rename; object_uuid=fo-55f3a83cada29fea |
| 266,020 | consensus_match | altLabel | [{"@value":"DFP","@language":"en","source":{"prov:wasGeneratedBy":"chebi_altlabels","prov:wasAttributedTo":"consensus-f… | [{"@value":"DFP","@language":"en","source":{"prov:wasGeneratedBy":"chebi_altlabels","prov:wasAttributedTo":"consensus-f… | group_key=diisopropylphosphorofluoridate||dimension=Environmental > media=Air > strata=Long-term; cas=55-91-4; added Common Chemistry CAS names as altLabel: <em>O</em>,<em>O</em>-Diisopropyl phosphorofluoridate, DFF, DFP (pesticide), Difluorophate, Diflupyl, Dyflos, Floropryl, Fluostigmine, Isopropyl fluophosphate ((C<sub>3</sub>H<sub>7</sub>O)<sub>2</sub>FPO), Isopropyl phosphorofluoridate ((C<sub>3</sub>H<sub>7</sub>O)<sub>2</sub>FPO), MeSH ID: D007531, Phosphorofluoridic acid, bis(1-methylethyl) ester, Phosphorofluoridic acid, diisopropyl ester; object_uuid=fo-55f3a83cada29fea |
| 266,021 | consensus_match | cas_match_labels | — | {"55-91-4":"exactMatch"} | group_key=diisopropylphosphorofluoridate||dimension=Environmental > media=Air > strata=Long-term; group_sources=['chebi', 'ec_inventory', 'pubchem']; cas_sources={'55-91-4': ['chebi', 'ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-55f3a83cada29fea: {'55-91-4': 'exactMatch'} |
| 276,948 | opsin_iupac | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6H14FO3P"… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6H14FO3P"… | opsin_iupac: set authoritative IUPAC name, SMILES, InChI from 'Diisopropyl fluorophosphate' |
| 283,598 | rdkit_post_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6H14FO3P"… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6H14FO3P"… | rdkit_post_consensus from 'CC(C)OP(=O)(F)OC(C)C'; confirmed: smiles_string, inchi2d_string, inchi2d_key_string, molecular_formula, molecular_mass, monoisotopic_mass |
| 292,639 | dedupe_altlabels | altLabel | [{"@value":"DFP","@language":"en","source":{"prov:wasGeneratedBy":"chebi_altlabels","prov:wasAttributedTo":"consensus-f… | [{"@value":"DFP","@language":"en","source":{"prov:wasGeneratedBy":"chebi_altlabels","prov:wasAttributedTo":"consensus-f… | Deduplicated altLabel values and removed entries matching prefLabel |
| 320,851 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/4031cd4c-d8ba-… | associations resolved on the elementary layer |
| 391,305 | normalise_property_values | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6H14FO3P"… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6H14FO3P"… | typed the way the ontology types it |
| 399,275 | link_flows_to_their_substance | types | — | ["https://w3id.org/chemrof/NeutralMolecule"] | the substance's answer, copied onto its flow |
PROV-O trail
22 activitiesOne activity per change: which version of the flow it consumed, and which it produced. The values are on the change with the same number — stored once, not twice.
| Activity | Field | Agent | Used | Generated |
|---|---|---|---|---|
| ef:activity/change/20260822T0600486828500000/12608 | prefLabel | ef:agent/bootstrap_labels | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v0 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v1 |
| ef:activity/change/20260822T0600486828500000/12609 | name | ef:agent/bootstrap_labels | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v1 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v2 |
| ef:activity/change/20260822T0600486828500000/17124 | synonyms | ef:agent/bootstrap_labels | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v2 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v3 |
| ef:activity/change/20260822T0600486828500000/79676 | context | ef:agent/default_context_mapping | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v3 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v4 |
| ef:activity/change/20260822T0600486828500000/79677 | context_iri | ef:agent/default_context_mapping | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v4 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v5 |
| ef:activity/change/20260822T0600486828500000/217511 | unit_iri | ef:agent/unit_normalization | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v5 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v6 |
| ef:activity/change/20260822T0600486828500000/224019 | prefLabel | ef:agent/normalize_name_case | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v6 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v7 |
| ef:activity/change/20260822T0600486828500000/239158 | properties | ef:agent/enrich_references | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v7 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v8 |
| ef:activity/change/20260822T0600486828500000/239159 | skos_definition | ef:agent/enrich_references | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v8 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v9 |
| ef:activity/change/20260822T0600486828500000/239160 | references | ef:agent/enrich_references | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v9 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v10 |
| ef:activity/change/20260822T0600486828500000/251761 | properties | ef:agent/rdkit_pre_consensus | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v10 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v11 |
| ef:activity/change/20260822T0600486828500000/256113 | altLabel | ef:agent/chebi_altlabels | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v11 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v12 |
| ef:activity/change/20260822T0600486828500000/266018 | prefLabel | ef:agent/consensus_match | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v12 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v13 |
| ef:activity/change/20260822T0600486828500000/266019 | altLabel | ef:agent/consensus_match | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v13 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v14 |
| ef:activity/change/20260822T0600486828500000/266020 | altLabel | ef:agent/consensus_match | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v14 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v15 |
| ef:activity/change/20260822T0600486828500000/266021 | cas_match_labels | ef:agent/consensus_match | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v15 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v16 |
| ef:activity/change/20260822T0600486828500000/276948 | properties | ef:agent/opsin_iupac | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v16 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v17 |
| ef:activity/change/20260822T0600486828500000/283598 | properties | ef:agent/rdkit_post_consensus | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v17 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v18 |
| ef:activity/change/20260822T0600486828500000/292639 | altLabel | ef:agent/dedupe_altlabels | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v18 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v19 |
| ef:activity/change/20260822T0600486828500000/320851 | concept_associations | ef:agent/carry_associations_onto_flows | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v19 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v20 |
| ef:activity/change/20260822T0600486828500000/391305 | properties | ef:agent/normalise_property_values | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v20 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v21 |
| ef:activity/change/20260822T0600486828500000/399275 | types | ef:agent/link_flows_to_their_substance | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v21 | ef:flow/4031cd4c-d8ba-4f6a-8653-13147d1b3728/v22 |