Phosphinic Acid
Everything that changed this flow. Back to the flow
641516f6-c9f5-4615-8df3-b7d610505af8
By field
13 fields| Field | Changes | Written by | Latest note |
|---|---|---|---|
| properties | 6 | enrich_references, normalise_property_values, opsin_iupac, rdkit_post_consensus, rdkit_pre_consensus, withhold_ambiguous_mass | typed the way the ontology types it |
| altLabel | 2 | chebi_altlabels, consensus_match | group_key=phosphinicacid||dimension=Environmental > media=Ground > geography=Unknown; cas=6303-21-5; added Common Chemistry CAS names as altLabel: Dihydroxyphosphine, Hydroxyphosphine oxide, Phosphine oxide, hydroxy-, Phosphonous acid; object_uuid=fo-57de44e5c68a5ef4 |
| prefLabel | 2 | bootstrap_labels, normalize_name_case | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| cas_match_labels | 1 | consensus_match | group_key=phosphinicacid||dimension=Environmental > media=Ground > geography=Unknown; group_sources=['chebi', 'ec_inventory', 'pubchem']; cas_sources={'6303-21-5': ['chebi', 'ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-57de44e5c68a5ef4: {'6303-21-5': 'exactMatch'} |
| concept_associations | 1 | carry_associations_onto_flows | associations resolved on the elementary layer |
| context | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to lower stratosphere and upper troposphere |
| context_iri | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to lower stratosphere and upper troposphere |
| name | 1 | bootstrap_labels | Purged legacy name field to enforce prefLabel usage |
| references | 1 | enrich_references | Added references with provenance; cas_numbers=['6303-21-5']; matched_chebi_ids=['http://purl.obolibrary.org/obo/CHEBI_29031']; candidate_pubchem_cids=[22497, 4124402, 6326996, 11533206, 22358456]; selected_pubchem_cids=[6326996]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| skos_definition | 1 | enrich_references | Merged ChEBI/PubChem definitions into skos:definition |
| synonyms | 1 | bootstrap_labels | Removed legacy synonyms field in favor of structured labels |
| types | 1 | link_flows_to_their_substance | the substance's answer, copied onto its flow |
| unit_iri | 1 | unit_normalization | Unit IRI set from normalization of 'kg' |
Where several steps wrote one field, the last one won — and the log below shows the sequence.
Changes
20| # | Step | Field | From | To | Why |
|---|---|---|---|---|---|
| 11,377 | bootstrap_labels | prefLabel | — | [{"@value":"phosphinic acid","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:wasAttributedTo"… | Bootstrapped prefLabel from legacy name field |
| 11,378 | bootstrap_labels | name | phosphinic acid | — | Purged legacy name field to enforce prefLabel usage |
| 11,379 | bootstrap_labels | synonyms | ["inorganic","phosphinicacid","phosphinicacid50%"] | [] | Removed legacy synonyms field in favor of structured labels |
| 109,140 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Aircraft cruise height"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to lower stratosphere and upper troposphere |
| 109,141 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-aicrhe | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to lower stratosphere and upper troposphere |
| 217,110 | unit_normalization | unit_iri | — | https://vocab.brightway.one/units/unit/KiloGM | Unit IRI set from normalization of 'kg' |
| 223,751 | normalize_name_case | prefLabel | [{"@value":"phosphinic acid","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:wasAttributedTo"… | [{"@value":"Phosphinic Acid","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:wasAttributedTo"… | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| 237,998 | enrich_references | properties | {} | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["H2O2P+","H… | Added ChEBI/PubChem properties (chebi_ids=1, pubchem_cids=1) |
| 237,999 | enrich_references | skos_definition | — | [{"@value":"A phosphorus oxoacid that consists of a single pentavalent phosphorus covalently bound via single bonds to… | Merged ChEBI/PubChem definitions into skos:definition |
| 238,000 | enrich_references | references | [] | [{"@id":"gmelin:25147","provenance":{"prov:wasGeneratedBy":"enrich_references.chebi_xrefs","prov:wasAttributedTo":"cons… | Added references with provenance; cas_numbers=['6303-21-5']; matched_chebi_ids=['http://purl.obolibrary.org/obo/CHEBI_29031']; candidate_pubchem_cids=[22497, 4124402, 6326996, 11533206, 22358456]; selected_pubchem_cids=[6326996]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| 251,423 | rdkit_pre_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["H2O2P+","H… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["H2O2P+","H… | rdkit_pre_consensus from 'O[PH+]=O'; added: molecular_mass, monoisotopic_mass |
| 255,963 | chebi_altlabels | altLabel | [] | [{"@value":"H2PO(OH)","@language":"en","source":{"prov:wasGeneratedBy":"chebi_altlabels","prov:wasAttributedTo":"consen… | Added 11 ChEBI synonym(s) as altLabel from 1 linked ChEBI record(s) |
| 270,679 | consensus_match | altLabel | [{"@value":"H2PO(OH)","@language":"en","source":{"prov:wasGeneratedBy":"chebi_altlabels","prov:wasAttributedTo":"consen… | [{"@value":"H2PO(OH)","@language":"en","source":{"prov:wasGeneratedBy":"chebi_altlabels","prov:wasAttributedTo":"consen… | group_key=phosphinicacid||dimension=Environmental > media=Ground > geography=Unknown; cas=6303-21-5; added Common Chemistry CAS names as altLabel: Dihydroxyphosphine, Hydroxyphosphine oxide, Phosphine oxide, hydroxy-, Phosphonous acid; object_uuid=fo-57de44e5c68a5ef4 |
| 270,680 | consensus_match | cas_match_labels | — | {"6303-21-5":"exactMatch"} | group_key=phosphinicacid||dimension=Environmental > media=Ground > geography=Unknown; group_sources=['chebi', 'ec_inventory', 'pubchem']; cas_sources={'6303-21-5': ['chebi', 'ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-57de44e5c68a5ef4: {'6303-21-5': 'exactMatch'} |
| 276,602 | opsin_iupac | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["H2O2P+","H… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["H2O2P+","H… | opsin_iupac: set authoritative IUPAC name, SMILES, InChI from 'Phosphinic Acid' |
| 283,225 | rdkit_post_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["H2O2P+","H… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["H2O2P+","H… | rdkit_post_consensus from 'O=[PH2]O'; added: monoisotopic_mass; confirmed: smiles_string, inchi2d_string, inchi2d_key_string, molecular_formula, molecular_mass |
| 286,961 | withhold_ambiguous_mass | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["H2O2P+","H… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["H2O2P+","H… | withhold_ambiguous_mass: removed molecular_mass, monoisotopic_mass; the flow carries 2 candidate structures, so no one mass describes it |
| 335,568 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/641516f6-c9f5-… | associations resolved on the elementary layer |
| 390,959 | normalise_property_values | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["H2O2P+","H… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["H2O2P+","H… | typed the way the ontology types it |
| 398,799 | link_flows_to_their_substance | types | — | ["https://w3id.org/chemrof/NeutralMolecule"] | the substance's answer, copied onto its flow |
PROV-O trail
20 activitiesOne activity per change: which version of the flow it consumed, and which it produced. The values are on the change with the same number — stored once, not twice.
| Activity | Field | Agent | Used | Generated |
|---|---|---|---|---|
| ef:activity/change/20260821T1554374006150000/11377 | prefLabel | ef:agent/bootstrap_labels | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v0 | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v1 |
| ef:activity/change/20260821T1554374006150000/11378 | name | ef:agent/bootstrap_labels | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v1 | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v2 |
| ef:activity/change/20260821T1554374006150000/11379 | synonyms | ef:agent/bootstrap_labels | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v2 | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v3 |
| ef:activity/change/20260821T1554374006150000/109140 | context | ef:agent/default_context_mapping | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v3 | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v4 |
| ef:activity/change/20260821T1554374006150000/109141 | context_iri | ef:agent/default_context_mapping | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v4 | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v5 |
| ef:activity/change/20260821T1554374006150000/217110 | unit_iri | ef:agent/unit_normalization | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v5 | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v6 |
| ef:activity/change/20260821T1554374006150000/223751 | prefLabel | ef:agent/normalize_name_case | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v6 | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v7 |
| ef:activity/change/20260821T1554374006150000/237998 | properties | ef:agent/enrich_references | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v7 | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v8 |
| ef:activity/change/20260821T1554374006150000/237999 | skos_definition | ef:agent/enrich_references | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v8 | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v9 |
| ef:activity/change/20260821T1554374006150000/238000 | references | ef:agent/enrich_references | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v9 | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v10 |
| ef:activity/change/20260821T1554374006150000/251423 | properties | ef:agent/rdkit_pre_consensus | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v10 | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v11 |
| ef:activity/change/20260821T1554374006150000/255963 | altLabel | ef:agent/chebi_altlabels | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v11 | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v12 |
| ef:activity/change/20260821T1554374006150000/270679 | altLabel | ef:agent/consensus_match | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v12 | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v13 |
| ef:activity/change/20260821T1554374006150000/270680 | cas_match_labels | ef:agent/consensus_match | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v13 | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v14 |
| ef:activity/change/20260821T1554374006150000/276602 | properties | ef:agent/opsin_iupac | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v14 | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v15 |
| ef:activity/change/20260821T1554374006150000/283225 | properties | ef:agent/rdkit_post_consensus | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v15 | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v16 |
| ef:activity/change/20260821T1554374006150000/286961 | properties | ef:agent/withhold_ambiguous_mass | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v16 | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v17 |
| ef:activity/change/20260821T1554374006150000/335568 | concept_associations | ef:agent/carry_associations_onto_flows | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v17 | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v18 |
| ef:activity/change/20260821T1554374006150000/390959 | properties | ef:agent/normalise_property_values | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v18 | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v19 |
| ef:activity/change/20260821T1554374006150000/398799 | types | ef:agent/link_flows_to_their_substance | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v19 | ef:flow/641516f6-c9f5-4615-8df3-b7d610505af8/v20 |