Methyl [dimethoxy(methyl)silyl]methylcarbamate
Everything that changed this flow. Back to the flow
7a4aa7a4-0255-4e88-8437-9a08c8fe0dee
By field
13 fields| Field | Changes | Written by | Latest note |
|---|---|---|---|
| properties | 5 | enrich_references, opsin_iupac, rdkit_post_consensus, rdkit_pre_consensus, withhold_ambiguous_mass | withhold_ambiguous_mass: removed molecular_mass, monoisotopic_mass; the flow carries 2 candidate structures, so no one mass describes it |
| altLabel | 2 | consensus_match, dedupe_altlabels | Deduplicated altLabel values and removed entries matching prefLabel |
| prefLabel | 2 | bootstrap_labels, normalize_name_case | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| cas_match_labels | 1 | consensus_match | group_key=methyl[dimethoxy(methyl)silyl]methylcarbamate||dimension=Environmental > media=Water > water_body=Long-term; group_sources=[]; cas_sources={'23432-65-7': []}; assigned CAS labels from group consensus; object_uuid=fo-5ce970e45efbe417: {'23432-65-7': 'exactMatch'} |
| concept_associations | 1 | carry_associations_onto_flows | associations resolved on the elementary layer |
| context | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified (long-term) |
| context_iri | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified (long-term) |
| name | 1 | bootstrap_labels | Purged legacy name field to enforce prefLabel usage |
| references | 1 | enrich_references | Added references with provenance; cas_numbers=['23432-65-7']; matched_chebi_ids=[]; candidate_pubchem_cids=[22065733, 123858750]; selected_pubchem_cids=[22065733]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| skos_definition | 1 | enrich_references | Merged ChEBI/PubChem definitions into skos:definition |
| synonyms | 1 | bootstrap_labels | Removed legacy synonyms field in favor of structured labels |
| types | 1 | link_flows_to_their_substance | the substance's answer, copied onto its flow |
| unit_iri | 1 | unit_normalization | Unit IRI set from normalization of 'kg' |
Where several steps wrote one field, the last one won — and the log below shows the sequence.
Changes
19| # | Step | Field | From | To | Why |
|---|---|---|---|---|---|
| 15,584 | bootstrap_labels | prefLabel | — | [{"@value":"methyl [dimethoxy(methyl)silyl]methylcarbamate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap… | Bootstrapped prefLabel from legacy name field |
| 15,585 | bootstrap_labels | name | methyl [dimethoxy(methyl)silyl]methylcarbamate | — | Purged legacy name field to enforce prefLabel usage |
| 15,586 | bootstrap_labels | synonyms | ["organometallic"] | [] | Removed legacy synonyms field in favor of structured labels |
| 122,494 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Long-term"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified (long-term) |
| 122,495 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-lote | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified (long-term) |
| 218,465 | unit_normalization | unit_iri | — | https://vocab.brightway.one/units/unit/KiloGM | Unit IRI set from normalization of 'kg' |
| 224,681 | normalize_name_case | prefLabel | [{"@value":"methyl [dimethoxy(methyl)silyl]methylcarbamate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap… | [{"@value":"Methyl [dimethoxy(methyl)silyl]methylcarbamate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap… | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| 241,868 | enrich_references | properties | {} | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6H15NO4Si… | Added ChEBI/PubChem properties (chebi_ids=0, pubchem_cids=1) |
| 241,869 | enrich_references | skos_definition | — | [] | Merged ChEBI/PubChem definitions into skos:definition |
| 241,870 | enrich_references | references | [] | [{"@id":"http://jglobal.jst.go.jp/en/redirect?Nikkaji_No=J3.782.104G","provenance":{"prov:wasGeneratedBy":"enrich_refer… | Added references with provenance; cas_numbers=['23432-65-7']; matched_chebi_ids=[]; candidate_pubchem_cids=[22065733, 123858750]; selected_pubchem_cids=[22065733]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| 252,552 | rdkit_pre_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6H15NO4Si… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6H15NO4Si… | rdkit_pre_consensus from 'COC(=O)NC[Si](C)(OC)OC'; added: molecular_mass, monoisotopic_mass |
| 268,795 | consensus_match | altLabel | [] | [{"@value":"<em>N</em>-[Dimethoxymethylsilyl)methyl]-<em>O</em>-methyl carbamate","@language":"en","source":{"prov:wasG… | group_key=methyl[dimethoxy(methyl)silyl]methylcarbamate||dimension=Environmental > media=Water > water_body=Long-term; cas=23432-65-7; added Common Chemistry CAS names as altLabel: <em>N</em>-[Dimethoxymethylsilyl)methyl]-<em>O</em>-methyl carbamate, Carbamic acid, <em>N</em>-[(dimethoxymethylsilyl)methyl]-, methyl ester, Carbamic acid, [(dimethoxymethylsilyl)methyl]-, methyl ester, Geniosil XL 65, Methyl (dimethoxymethylsilyl)methylcarbamate, Methyl <em>N</em>-[(dimethoxymethylsilyl)methyl]carbamate, Methyl <em>N</em>-[[(dimethoxy)(methyl)silyl]methyl]carbamic acid, [(Methylcarbamato)methyl]dimethoxymethylsilane; object_uuid=fo-5ce970e45efbe417 |
| 268,796 | consensus_match | cas_match_labels | — | {"23432-65-7":"exactMatch"} | group_key=methyl[dimethoxy(methyl)silyl]methylcarbamate||dimension=Environmental > media=Water > water_body=Long-term; group_sources=[]; cas_sources={'23432-65-7': []}; assigned CAS labels from group consensus; object_uuid=fo-5ce970e45efbe417: {'23432-65-7': 'exactMatch'} |
| 277,758 | opsin_iupac | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6H15NO4Si… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6H15NO4Si… | opsin_iupac: set authoritative IUPAC name, SMILES, InChI from 'Carbamic acid, N-[(dimethoxymethylsilyl)methyl]-, methyl ester' |
| 284,457 | rdkit_post_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6H15NO4Si… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6H15NO4Si… | rdkit_post_consensus from 'COC(=O)NC[SiH2]C(OC)OC'; added: inchi2d_key_string; confirmed: smiles_string, inchi2d_string, molecular_formula, molecular_mass, monoisotopic_mass |
| 287,061 | withhold_ambiguous_mass | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6H15NO4Si… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C6H15NO4Si… | withhold_ambiguous_mass: removed molecular_mass, monoisotopic_mass; the flow carries 2 candidate structures, so no one mass describes it |
| 292,829 | dedupe_altlabels | altLabel | [{"@value":"<em>N</em>-[Dimethoxymethylsilyl)methyl]-<em>O</em>-methyl carbamate","@language":"en","source":{"prov:wasG… | [{"@value":"N-[Dimethoxymethylsilyl)methyl]-O-methyl carbamate","@language":"en","source":{"prov:wasGeneratedBy":"conse… | Deduplicated altLabel values and removed entries matching prefLabel |
| 342,245 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/7a4aa7a4-0255-… | associations resolved on the elementary layer |
| 400,424 | link_flows_to_their_substance | types | — | ["https://w3id.org/chemrof/NeutralMolecule"] | the substance's answer, copied onto its flow |
PROV-O trail
19 activitiesOne activity per change: which version of the flow it consumed, and which it produced. The values are on the change with the same number — stored once, not twice.
| Activity | Field | Agent | Used | Generated |
|---|---|---|---|---|
| ef:activity/change/20260822T0600486828500000/15584 | prefLabel | ef:agent/bootstrap_labels | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v0 | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v1 |
| ef:activity/change/20260822T0600486828500000/15585 | name | ef:agent/bootstrap_labels | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v1 | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v2 |
| ef:activity/change/20260822T0600486828500000/15586 | synonyms | ef:agent/bootstrap_labels | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v2 | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v3 |
| ef:activity/change/20260822T0600486828500000/122494 | context | ef:agent/default_context_mapping | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v3 | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v4 |
| ef:activity/change/20260822T0600486828500000/122495 | context_iri | ef:agent/default_context_mapping | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v4 | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v5 |
| ef:activity/change/20260822T0600486828500000/218465 | unit_iri | ef:agent/unit_normalization | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v5 | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v6 |
| ef:activity/change/20260822T0600486828500000/224681 | prefLabel | ef:agent/normalize_name_case | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v6 | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v7 |
| ef:activity/change/20260822T0600486828500000/241868 | properties | ef:agent/enrich_references | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v7 | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v8 |
| ef:activity/change/20260822T0600486828500000/241869 | skos_definition | ef:agent/enrich_references | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v8 | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v9 |
| ef:activity/change/20260822T0600486828500000/241870 | references | ef:agent/enrich_references | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v9 | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v10 |
| ef:activity/change/20260822T0600486828500000/252552 | properties | ef:agent/rdkit_pre_consensus | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v10 | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v11 |
| ef:activity/change/20260822T0600486828500000/268795 | altLabel | ef:agent/consensus_match | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v11 | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v12 |
| ef:activity/change/20260822T0600486828500000/268796 | cas_match_labels | ef:agent/consensus_match | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v12 | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v13 |
| ef:activity/change/20260822T0600486828500000/277758 | properties | ef:agent/opsin_iupac | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v13 | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v14 |
| ef:activity/change/20260822T0600486828500000/284457 | properties | ef:agent/rdkit_post_consensus | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v14 | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v15 |
| ef:activity/change/20260822T0600486828500000/287061 | properties | ef:agent/withhold_ambiguous_mass | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v15 | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v16 |
| ef:activity/change/20260822T0600486828500000/292829 | altLabel | ef:agent/dedupe_altlabels | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v16 | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v17 |
| ef:activity/change/20260822T0600486828500000/342245 | concept_associations | ef:agent/carry_associations_onto_flows | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v17 | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v18 |
| ef:activity/change/20260822T0600486828500000/400424 | types | ef:agent/link_flows_to_their_substance | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v18 | ef:flow/7a4aa7a4-0255-4e88-8437-9a08c8fe0dee/v19 |