6,6'-[(3,3'-di-tert-butyl-5,5'-dimethoxybiphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepine)
Everything that changed this flow. Back to the flow
81ed663f-eb80-42a8-b289-ea0c51de69c9
By field
13 fields| Field | Changes | Written by | Latest note |
|---|---|---|---|
| properties | 5 | enrich_references, normalise_property_values, opsin_iupac, rdkit_post_consensus, rdkit_pre_consensus | typed the way the ontology types it |
| altLabel | 2 | consensus_match, dedupe_altlabels | Deduplicated altLabel values and removed entries matching prefLabel |
| cas_match_labels | 1 | consensus_match | group_key=6,6'-[(3,3'-di-tert-butyl-5,5'-dimethoxybiphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepine)||dimension=Environmental > media=Water > water_body=Unknown; group_sources=[]; cas_sources={'121627-17-6': []}; assigned CAS labels from group consensus; object_uuid=fo-375bfbf78694ff82: {'121627-17-6': 'exactMatch'} |
| concept_associations | 1 | carry_associations_onto_flows | associations resolved on the elementary layer |
| context | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified (long-term) |
| context_iri | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified (long-term) |
| name | 1 | bootstrap_labels | Purged legacy name field to enforce prefLabel usage |
| prefLabel | 1 | bootstrap_labels | Bootstrapped prefLabel from legacy name field |
| references | 1 | enrich_references | Added references with provenance; cas_numbers=['121627-17-6']; matched_chebi_ids=[]; candidate_pubchem_cids=[10865829, 71310693, 176447382]; selected_pubchem_cids=[10865829]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| skos_definition | 1 | enrich_references | Merged ChEBI/PubChem definitions into skos:definition |
| synonyms | 1 | bootstrap_labels | Removed legacy synonyms field in favor of structured labels |
| types | 1 | link_flows_to_their_substance | the substance's answer, copied onto its flow |
| unit_iri | 1 | unit_normalization | Unit IRI set from normalization of 'kg' |
Where several steps wrote one field, the last one won — and the log below shows the sequence.
Changes
18| # | Step | Field | From | To | Why |
|---|---|---|---|---|---|
| 17,760 | bootstrap_labels | prefLabel | — | [{"@value":"6,6'-[(3,3'-di-tert-butyl-5,5'-dimethoxybiphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepine… | Bootstrapped prefLabel from legacy name field |
| 17,761 | bootstrap_labels | name | 6,6'-[(3,3'-di-tert-butyl-5,5'-dimethoxybiphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepine) | — | Purged legacy name field to enforce prefLabel usage |
| 17,762 | bootstrap_labels | synonyms | ["organic","ligandl017"] | [] | Removed legacy synonyms field in favor of structured labels |
| 127,010 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Long-term"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified (long-term) |
| 127,011 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-lote | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, unspecified (long-term) |
| 219,155 | unit_normalization | unit_iri | — | https://vocab.brightway.one/units/unit/KiloGM | Unit IRI set from normalization of 'kg' |
| 243,814 | enrich_references | properties | {} | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C46H44O8P2… | Added ChEBI/PubChem properties (chebi_ids=0, pubchem_cids=1) |
| 243,815 | enrich_references | skos_definition | — | [] | Merged ChEBI/PubChem definitions into skos:definition |
| 243,816 | enrich_references | references | [] | [{"@id":"http://jglobal.jst.go.jp/en/redirect?Nikkaji_No=J1.143.243C","provenance":{"prov:wasGeneratedBy":"enrich_refer… | Added references with provenance; cas_numbers=['121627-17-6']; matched_chebi_ids=[]; candidate_pubchem_cids=[10865829, 71310693, 176447382]; selected_pubchem_cids=[10865829]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| 253,109 | rdkit_pre_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C46H44O8P2… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C46H44O8P2… | rdkit_pre_consensus from 'CC(C)(C)C1=CC(=CC(=C1OP2OC3=CC=CC=C3C4=CC=CC=C4O2)C5=C(C(=CC(=C5)OC)C(C)(C)C)OP6OC7=CC=CC=C7C8=CC=CC=C8O6)OC'; added: molecular_mass, monoisotopic_mass |
| 263,188 | consensus_match | altLabel | [] | [{"@value":"2,2′-Bis[(1,1′-biphenyl-2,2′-diyl)phosphite]-3,3′-di-<em>tert</em>-butyl-5,5′-dimethoxy-1,1′-biphenyl","@la… | group_key=6,6'-[(3,3'-di-tert-butyl-5,5'-dimethoxybiphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepine)||dimension=Environmental > media=Water > water_body=Unknown; cas=121627-17-6; added Common Chemistry CAS names as altLabel: 2,2′-Bis[(1,1′-biphenyl-2,2′-diyl)phosphite]-3,3′-di-<em>tert</em>-butyl-5,5′-dimethoxy-1,1′-biphenyl, 6,6′-[[3,3′-Bis(1,1-dimethylethyl)-5,5′-dimethoxy[1,1′-biphenyl]-2,2′-diyl]bis(oxy)]bis[dibenzo[<em>d</em>,<em>f</em>][1,3,2]dioxaphosphepin], BIPHEPHOS, Dibenzo[<em>d</em>,<em>f</em>][1,3,2]dioxaphosphepin, 6,6′-[[3,3′-bis(1,1-dimethylethyl)-5,5′-dimethoxy[1,1′-biphenyl]-2,2′-diyl]bis(oxy)]bis-, Oxophos 17; object_uuid=fo-375bfbf78694ff82 |
| 263,189 | consensus_match | cas_match_labels | — | {"121627-17-6":"exactMatch"} | group_key=6,6'-[(3,3'-di-tert-butyl-5,5'-dimethoxybiphenyl-2,2'-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepine)||dimension=Environmental > media=Water > water_body=Unknown; group_sources=[]; cas_sources={'121627-17-6': []}; assigned CAS labels from group consensus; object_uuid=fo-375bfbf78694ff82: {'121627-17-6': 'exactMatch'} |
| 278,312 | opsin_iupac | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C46H44O8P2… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C46H44O8P2… | opsin_iupac: set authoritative IUPAC name, SMILES, InChI from 'Dibenzo[d,f][1,3,2]dioxaphosphepin, 6,6′-[[3,3′-bis(1,1-dimethylethyl)-5,5′-dimethoxy[1,1′-biphenyl]-2,2′-diyl]bis(oxy)]bis-' |
| 285,065 | rdkit_post_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C46H44O8P2… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C46H44O8P2… | rdkit_post_consensus from 'COc1cc(-c2cc(OC)cc(C(C)(C)C)c2Op2oc3ccccc3c3ccccc3o2)c(Op2oc3ccccc3c3ccccc3o2)c(C(C)(C)C)c1'; confirmed: smiles_string, inchi2d_string, inchi2d_key_string, molecular_formula, molecular_mass, monoisotopic_mass |
| 292,961 | dedupe_altlabels | altLabel | [{"@value":"2,2′-Bis[(1,1′-biphenyl-2,2′-diyl)phosphite]-3,3′-di-<em>tert</em>-butyl-5,5′-dimethoxy-1,1′-biphenyl","@la… | [{"@value":"2,2′-Bis[(1,1′-biphenyl-2,2′-diyl)phosphite]-3,3′-di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl","@language":"… | Deduplicated altLabel values and removed entries matching prefLabel |
| 344,507 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/81ed663f-eb80-… | associations resolved on the elementary layer |
| 392,672 | normalise_property_values | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C46H44O8P2… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C46H44O8P2… | typed the way the ontology types it |
| 401,261 | link_flows_to_their_substance | types | — | ["https://w3id.org/chemrof/NeutralMolecule"] | the substance's answer, copied onto its flow |
PROV-O trail
18 activitiesOne activity per change: which version of the flow it consumed, and which it produced. The values are on the change with the same number — stored once, not twice.
| Activity | Field | Agent | Used | Generated |
|---|---|---|---|---|
| ef:activity/change/20260821T1554374006150000/17760 | prefLabel | ef:agent/bootstrap_labels | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v0 | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v1 |
| ef:activity/change/20260821T1554374006150000/17761 | name | ef:agent/bootstrap_labels | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v1 | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v2 |
| ef:activity/change/20260821T1554374006150000/17762 | synonyms | ef:agent/bootstrap_labels | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v2 | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v3 |
| ef:activity/change/20260821T1554374006150000/127010 | context | ef:agent/default_context_mapping | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v3 | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v4 |
| ef:activity/change/20260821T1554374006150000/127011 | context_iri | ef:agent/default_context_mapping | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v4 | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v5 |
| ef:activity/change/20260821T1554374006150000/219155 | unit_iri | ef:agent/unit_normalization | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v5 | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v6 |
| ef:activity/change/20260821T1554374006150000/243814 | properties | ef:agent/enrich_references | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v6 | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v7 |
| ef:activity/change/20260821T1554374006150000/243815 | skos_definition | ef:agent/enrich_references | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v7 | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v8 |
| ef:activity/change/20260821T1554374006150000/243816 | references | ef:agent/enrich_references | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v8 | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v9 |
| ef:activity/change/20260821T1554374006150000/253109 | properties | ef:agent/rdkit_pre_consensus | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v9 | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v10 |
| ef:activity/change/20260821T1554374006150000/263188 | altLabel | ef:agent/consensus_match | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v10 | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v11 |
| ef:activity/change/20260821T1554374006150000/263189 | cas_match_labels | ef:agent/consensus_match | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v11 | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v12 |
| ef:activity/change/20260821T1554374006150000/278312 | properties | ef:agent/opsin_iupac | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v12 | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v13 |
| ef:activity/change/20260821T1554374006150000/285065 | properties | ef:agent/rdkit_post_consensus | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v13 | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v14 |
| ef:activity/change/20260821T1554374006150000/292961 | altLabel | ef:agent/dedupe_altlabels | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v14 | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v15 |
| ef:activity/change/20260821T1554374006150000/344507 | concept_associations | ef:agent/carry_associations_onto_flows | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v15 | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v16 |
| ef:activity/change/20260821T1554374006150000/392672 | properties | ef:agent/normalise_property_values | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v16 | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v17 |
| ef:activity/change/20260821T1554374006150000/401261 | types | ef:agent/link_flows_to_their_substance | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v17 | ef:flow/81ed663f-eb80-42a8-b289-ea0c51de69c9/v18 |