Bis(2,4,4-trimethylpentyl)phosphinic Acid
Everything that changed this flow. Back to the flow
8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63
By field
13 fields| Field | Changes | Written by | Latest note |
|---|---|---|---|
| properties | 5 | enrich_references, normalise_property_values, opsin_iupac, rdkit_post_consensus, rdkit_pre_consensus | typed the way the ontology types it |
| altLabel | 2 | consensus_match, strip_catalogue_altlabels | Removed 3 catalogue altLabel value(s): 'Cyanex 272' (trade name), 'Cymanex 272' (trade name), 'Ionquest 290' (trade name) |
| prefLabel | 2 | bootstrap_labels, normalize_name_case | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| cas_match_labels | 1 | consensus_match | group_key=bis(2,4,4-trimethylpentyl)phosphinicacid||dimension=Environmental > media=Air > indoor=Unknown; group_sources=['ec_inventory', 'pubchem']; cas_sources={'83411-71-6': ['ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-9292e12fae4d5126: {'83411-71-6': 'exactMatch'} |
| concept_associations | 1 | carry_associations_onto_flows | associations resolved on the elementary layer |
| context | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to sea water |
| context_iri | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to sea water |
| name | 1 | bootstrap_labels | Purged legacy name field to enforce prefLabel usage |
| references | 1 | enrich_references | Added references with provenance; cas_numbers=['83411-71-6']; matched_chebi_ids=[]; candidate_pubchem_cids=[157898, 251433, 13629073, 86306264]; selected_pubchem_cids=[157898]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| skos_definition | 1 | enrich_references | Merged ChEBI/PubChem definitions into skos:definition |
| synonyms | 1 | bootstrap_labels | Removed legacy synonyms field in favor of structured labels |
| types | 1 | link_flows_to_their_substance | the substance's answer, copied onto its flow |
| unit_iri | 1 | unit_normalization | Unit IRI set from normalization of 'kg' |
Where several steps wrote one field, the last one won — and the log below shows the sequence.
Changes
19| # | Step | Field | From | To | Why |
|---|---|---|---|---|---|
| 4,290 | bootstrap_labels | prefLabel | — | [{"@value":"bis(2,4,4-trimethylpentyl)phosphinic acid","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labe… | Bootstrapped prefLabel from legacy name field |
| 4,291 | bootstrap_labels | name | bis(2,4,4-trimethylpentyl)phosphinic acid | — | Purged legacy name field to enforce prefLabel usage |
| 4,292 | bootstrap_labels | synonyms | ["organic","bis(2,4,4-trimethylpentyl)phosphinicacid","cyanexâ®272extractant"] | [] | Removed legacy synonyms field in favor of structured labels |
| 135,264 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Water","water_body":"Ocean"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to sea water |
| 135,265 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-wate-ocea | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to water > Emissions to sea water |
| 214,772 | unit_normalization | unit_iri | — | https://vocab.brightway.one/units/unit/KiloGM | Unit IRI set from normalization of 'kg' |
| 222,080 | normalize_name_case | prefLabel | [{"@value":"bis(2,4,4-trimethylpentyl)phosphinic acid","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labe… | [{"@value":"Bis(2,4,4-trimethylpentyl)phosphinic Acid","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labe… | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| 231,306 | enrich_references | properties | {} | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C16H35O2P"… | Added ChEBI/PubChem properties (chebi_ids=0, pubchem_cids=1) |
| 231,307 | enrich_references | skos_definition | — | [] | Merged ChEBI/PubChem definitions into skos:definition |
| 231,308 | enrich_references | references | [] | [{"@id":"http://jglobal.jst.go.jp/en/redirect?Nikkaji_No=J326.801B","provenance":{"prov:wasGeneratedBy":"enrich_referen… | Added references with provenance; cas_numbers=['83411-71-6']; matched_chebi_ids=[]; candidate_pubchem_cids=[157898, 251433, 13629073, 86306264]; selected_pubchem_cids=[157898]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| 249,504 | rdkit_pre_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C16H35O2P"… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C16H35O2P"… | rdkit_pre_consensus from 'CC(CC(C)(C)C)CP(=O)(CC(C)CC(C)(C)C)O'; added: molecular_mass, monoisotopic_mass |
| 264,300 | consensus_match | altLabel | [] | [{"@value":"<em>P</em>,<em>P</em>-Bis(2,4,4-trimethylpentyl)phosphinic acid","@language":"en","source":{"prov:wasGenera… | group_key=bis(2,4,4-trimethylpentyl)phosphinicacid||dimension=Environmental > media=Air > indoor=Unknown; cas=83411-71-6; added Common Chemistry CAS names as altLabel: <em>P</em>,<em>P</em>-Bis(2,4,4-trimethylpentyl)phosphinic acid, Cyanex 272, Cymanex 272, DZ-Ni-EX 01, HBTMPP, Ionquest 290, Phosphinic acid, <em>P</em>,<em>P</em>-bis(2,4,4-trimethylpentyl)-, Phosphinic acid, bis(2,4,4-trimethylpentyl)-; object_uuid=fo-9292e12fae4d5126 |
| 264,301 | consensus_match | cas_match_labels | — | {"83411-71-6":"exactMatch"} | group_key=bis(2,4,4-trimethylpentyl)phosphinicacid||dimension=Environmental > media=Air > indoor=Unknown; group_sources=['ec_inventory', 'pubchem']; cas_sources={'83411-71-6': ['ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-9292e12fae4d5126: {'83411-71-6': 'exactMatch'} |
| 274,636 | opsin_iupac | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C16H35O2P"… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C16H35O2P"… | opsin_iupac: set authoritative IUPAC name, SMILES, InChI from 'Bis(2,4,4-trimethylpentyl)phosphinic Acid' |
| 281,091 | rdkit_post_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C16H35O2P"… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C16H35O2P"… | rdkit_post_consensus from 'CC(CC(C)(C)C)CP(=O)(O)CC(C)CC(C)(C)C'; confirmed: smiles_string, inchi2d_string, inchi2d_key_string, molecular_formula, molecular_mass, monoisotopic_mass |
| 288,128 | strip_catalogue_altlabels | altLabel | [{"@value":"<em>P</em>,<em>P</em>-Bis(2,4,4-trimethylpentyl)phosphinic acid","@language":"en","source":{"prov:wasGenera… | [{"@value":"P,P-Bis(2,4,4-trimethylpentyl)phosphinic acid","@language":"en","source":{"prov:wasGeneratedBy":"consensus_… | Removed 3 catalogue altLabel value(s): 'Cyanex 272' (trade name), 'Cymanex 272' (trade name), 'Ionquest 290' (trade name) |
| 348,628 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/8fd2a89f-b3b4-… | associations resolved on the elementary layer |
| 388,941 | normalise_property_values | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C16H35O2P"… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C16H35O2P"… | typed the way the ontology types it |
| 395,890 | link_flows_to_their_substance | types | — | ["https://w3id.org/chemrof/NeutralMolecule"] | the substance's answer, copied onto its flow |
PROV-O trail
19 activitiesOne activity per change: which version of the flow it consumed, and which it produced. The values are on the change with the same number — stored once, not twice.
| Activity | Field | Agent | Used | Generated |
|---|---|---|---|---|
| ef:activity/change/20260821T1554374006150000/4290 | prefLabel | ef:agent/bootstrap_labels | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v0 | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v1 |
| ef:activity/change/20260821T1554374006150000/4291 | name | ef:agent/bootstrap_labels | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v1 | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v2 |
| ef:activity/change/20260821T1554374006150000/4292 | synonyms | ef:agent/bootstrap_labels | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v2 | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v3 |
| ef:activity/change/20260821T1554374006150000/135264 | context | ef:agent/default_context_mapping | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v3 | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v4 |
| ef:activity/change/20260821T1554374006150000/135265 | context_iri | ef:agent/default_context_mapping | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v4 | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v5 |
| ef:activity/change/20260821T1554374006150000/214772 | unit_iri | ef:agent/unit_normalization | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v5 | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v6 |
| ef:activity/change/20260821T1554374006150000/222080 | prefLabel | ef:agent/normalize_name_case | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v6 | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v7 |
| ef:activity/change/20260821T1554374006150000/231306 | properties | ef:agent/enrich_references | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v7 | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v8 |
| ef:activity/change/20260821T1554374006150000/231307 | skos_definition | ef:agent/enrich_references | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v8 | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v9 |
| ef:activity/change/20260821T1554374006150000/231308 | references | ef:agent/enrich_references | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v9 | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v10 |
| ef:activity/change/20260821T1554374006150000/249504 | properties | ef:agent/rdkit_pre_consensus | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v10 | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v11 |
| ef:activity/change/20260821T1554374006150000/264300 | altLabel | ef:agent/consensus_match | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v11 | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v12 |
| ef:activity/change/20260821T1554374006150000/264301 | cas_match_labels | ef:agent/consensus_match | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v12 | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v13 |
| ef:activity/change/20260821T1554374006150000/274636 | properties | ef:agent/opsin_iupac | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v13 | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v14 |
| ef:activity/change/20260821T1554374006150000/281091 | properties | ef:agent/rdkit_post_consensus | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v14 | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v15 |
| ef:activity/change/20260821T1554374006150000/288128 | altLabel | ef:agent/strip_catalogue_altlabels | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v15 | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v16 |
| ef:activity/change/20260821T1554374006150000/348628 | concept_associations | ef:agent/carry_associations_onto_flows | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v16 | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v17 |
| ef:activity/change/20260821T1554374006150000/388941 | properties | ef:agent/normalise_property_values | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v17 | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v18 |
| ef:activity/change/20260821T1554374006150000/395890 | types | ef:agent/link_flows_to_their_substance | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v18 | ef:flow/8fd2a89f-b3b4-44dd-bf5e-b013e3ae9c63/v19 |