O,O,O',O'-tetrapropyl Pyrophosphorothioate
Everything that changed this flow. Back to the flow
ca1026ec-6911-47d5-9a39-b0e2f54340a1
By field
13 fields| Field | Changes | Written by | Latest note |
|---|---|---|---|
| properties | 5 | enrich_references, normalise_property_values, opsin_iupac, rdkit_post_consensus, rdkit_pre_consensus | typed the way the ontology types it |
| altLabel | 2 | consensus_match, strip_catalogue_altlabels | Removed 4 catalogue altLabel value(s): 'A 42' (grade code), 'ASP 51' (grade code), 'E 8573' (grade code), 'NSC 2550' (registry code) |
| prefLabel | 2 | bootstrap_labels, normalize_name_case | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| cas_match_labels | 1 | consensus_match | group_key=o,o,o',o'-tetrapropylpyrophosphorothioate||dimension=Environmental > media=Air > strata=Long-term; group_sources=['ec_inventory', 'pubchem']; cas_sources={'3244-90-4': ['ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-b825b3dbc181863b: {'3244-90-4': 'exactMatch'} |
| concept_associations | 1 | carry_associations_onto_flows | associations resolved on the elementary layer |
| context | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to agricultural soil |
| context_iri | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to agricultural soil |
| name | 1 | bootstrap_labels | Purged legacy name field to enforce prefLabel usage |
| references | 1 | enrich_references | Added references with provenance; cas_numbers=['3244-90-4']; matched_chebi_ids=[]; candidate_pubchem_cids=[18609]; selected_pubchem_cids=[18609]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| skos_definition | 1 | enrich_references | Merged ChEBI/PubChem definitions into skos:definition |
| synonyms | 1 | bootstrap_labels | Removed legacy synonyms field in favor of structured labels |
| types | 1 | link_flows_to_their_substance | the substance's answer, copied onto its flow |
| unit_iri | 1 | unit_normalization | Unit IRI set from normalization of 'kg' |
Where several steps wrote one field, the last one won — and the log below shows the sequence.
Changes
19| # | Step | Field | From | To | Why |
|---|---|---|---|---|---|
| 6,521 | bootstrap_labels | prefLabel | — | [{"@value":"O,O,O',O'-tetrapropyl pyrophosphorothioate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_lab… | Bootstrapped prefLabel from legacy name field |
| 6,522 | bootstrap_labels | name | O,O,O',O'-tetrapropyl pyrophosphorothioate | — | Purged legacy name field to enforce prefLabel usage |
| 6,523 | bootstrap_labels | synonyms | ["A 42","A 42 (VAN)","AC1L2CFI","ASP 51","ASPON","Bis(O,O-di(N-propyl))phosphorothionic anhydride","Bis-O,O-di-n-propyl… | [] | Removed legacy synonyms field in favor of structured labels |
| 169,438 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Ground","geography":"Agricultural"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to agricultural soil |
| 169,439 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-grou-agri | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to agricultural soil |
| 215,516 | unit_normalization | unit_iri | — | https://vocab.brightway.one/units/unit/KiloGM | Unit IRI set from normalization of 'kg' |
| 222,589 | normalize_name_case | prefLabel | [{"@value":"O,O,O',O'-tetrapropyl pyrophosphorothioate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_lab… | [{"@value":"O,O,O',O'-tetrapropyl Pyrophosphorothioate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_lab… | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| 233,442 | enrich_references | properties | {} | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C12H28O5P2… | Added ChEBI/PubChem properties (chebi_ids=0, pubchem_cids=1) |
| 233,443 | enrich_references | skos_definition | — | [] | Merged ChEBI/PubChem definitions into skos:definition |
| 233,444 | enrich_references | references | [] | [{"@id":"http://jglobal.jst.go.jp/en/redirect?Nikkaji_No=J7.697J","provenance":{"prov:wasGeneratedBy":"enrich_reference… | Added references with provenance; cas_numbers=['3244-90-4']; matched_chebi_ids=[]; candidate_pubchem_cids=[18609]; selected_pubchem_cids=[18609]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| 250,121 | rdkit_pre_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C12H28O5P2… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C12H28O5P2… | rdkit_pre_consensus from 'CCCOP(=S)(OCCC)OP(=S)(OCCC)OCCC'; added: molecular_mass, monoisotopic_mass |
| 269,972 | consensus_match | altLabel | [] | [{"@value":"<em>O</em>,<em>O</em>,<em>O</em>,<em>O</em>-Tetrapropyl dithiopyrophosphate","@language":"en","source":{"pr… | group_key=o,o,o',o'-tetrapropylpyrophosphorothioate||dimension=Environmental > media=Air > strata=Long-term; cas=3244-90-4; added Common Chemistry CAS names as altLabel: <em>O</em>,<em>O</em>,<em>O</em>,<em>O</em>-Tetrapropyl dithiopyrophosphate, A 42, ASP 51, Aspon, E 8573, NPD, NSC 2550, Propyl thiopyrophosphate ([(PrO)<sub>2</sub>P(S)]<sub>2</sub>O), Tetra-<em>n</em>-propyl dithionopyrophosphate, Tetra-<em>n</em>-propyl dithiopyrophosphate, Thiodiphosphoric acid ([(HO)<sub>2</sub>P(S)]<sub>2</sub>O), <em>O</em><sup>P</sup>,<em>O</em><sup>P</sup>,<em>O</em><sup>P′</sup>,<em>O</em><sup>P′</sup>-tetrapropyl ester, Thiodiphosphoric acid ([(HO)<sub>2</sub>P(S)]<sub>2</sub>O), tetrapropyl ester, Thiopyrophosphoric acid ([(HO)<sub>2</sub>PS]<sub>2</sub>O), tetrapropyl ester; object_uuid=fo-b825b3dbc181863b |
| 269,973 | consensus_match | cas_match_labels | — | {"3244-90-4":"exactMatch"} | group_key=o,o,o',o'-tetrapropylpyrophosphorothioate||dimension=Environmental > media=Air > strata=Long-term; group_sources=['ec_inventory', 'pubchem']; cas_sources={'3244-90-4': ['ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-b825b3dbc181863b: {'3244-90-4': 'exactMatch'} |
| 275,258 | opsin_iupac | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C12H28O5P2… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C12H28O5P2… | opsin_iupac: set authoritative IUPAC name, SMILES, InChI from 'O,O,O,O-Tetrapropyl dithiopyrophosphate' |
| 281,764 | rdkit_post_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C12H28O5P2… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C12H28O5P2… | rdkit_post_consensus from 'CCCOP(=S)(OCCC)OP(=S)(OCCC)OCCC'; confirmed: smiles_string, inchi2d_string, inchi2d_key_string, molecular_formula, molecular_mass, monoisotopic_mass |
| 288,584 | strip_catalogue_altlabels | altLabel | [{"@value":"<em>O</em>,<em>O</em>,<em>O</em>,<em>O</em>-Tetrapropyl dithiopyrophosphate","@language":"en","source":{"pr… | [{"@value":"O,O,O,O-Tetrapropyl dithiopyrophosphate","@language":"en","source":{"prov:wasGeneratedBy":"consensus_match"… | Removed 4 catalogue altLabel value(s): 'A 42' (grade code), 'ASP 51' (grade code), 'E 8573' (grade code), 'NSC 2550' (registry code) |
| 365,745 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/ca1026ec-6911-… | associations resolved on the elementary layer |
| 389,561 | normalise_property_values | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C12H28O5P2… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C12H28O5P2… | typed the way the ontology types it |
| 396,764 | link_flows_to_their_substance | types | — | ["https://w3id.org/chemrof/NeutralMolecule"] | the substance's answer, copied onto its flow |
PROV-O trail
19 activitiesOne activity per change: which version of the flow it consumed, and which it produced. The values are on the change with the same number — stored once, not twice.
| Activity | Field | Agent | Used | Generated |
|---|---|---|---|---|
| ef:activity/change/20260822T0600486828500000/6521 | prefLabel | ef:agent/bootstrap_labels | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v0 | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v1 |
| ef:activity/change/20260822T0600486828500000/6522 | name | ef:agent/bootstrap_labels | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v1 | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v2 |
| ef:activity/change/20260822T0600486828500000/6523 | synonyms | ef:agent/bootstrap_labels | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v2 | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v3 |
| ef:activity/change/20260822T0600486828500000/169438 | context | ef:agent/default_context_mapping | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v3 | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v4 |
| ef:activity/change/20260822T0600486828500000/169439 | context_iri | ef:agent/default_context_mapping | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v4 | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v5 |
| ef:activity/change/20260822T0600486828500000/215516 | unit_iri | ef:agent/unit_normalization | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v5 | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v6 |
| ef:activity/change/20260822T0600486828500000/222589 | prefLabel | ef:agent/normalize_name_case | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v6 | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v7 |
| ef:activity/change/20260822T0600486828500000/233442 | properties | ef:agent/enrich_references | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v7 | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v8 |
| ef:activity/change/20260822T0600486828500000/233443 | skos_definition | ef:agent/enrich_references | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v8 | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v9 |
| ef:activity/change/20260822T0600486828500000/233444 | references | ef:agent/enrich_references | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v9 | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v10 |
| ef:activity/change/20260822T0600486828500000/250121 | properties | ef:agent/rdkit_pre_consensus | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v10 | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v11 |
| ef:activity/change/20260822T0600486828500000/269972 | altLabel | ef:agent/consensus_match | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v11 | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v12 |
| ef:activity/change/20260822T0600486828500000/269973 | cas_match_labels | ef:agent/consensus_match | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v12 | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v13 |
| ef:activity/change/20260822T0600486828500000/275258 | properties | ef:agent/opsin_iupac | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v13 | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v14 |
| ef:activity/change/20260822T0600486828500000/281764 | properties | ef:agent/rdkit_post_consensus | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v14 | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v15 |
| ef:activity/change/20260822T0600486828500000/288584 | altLabel | ef:agent/strip_catalogue_altlabels | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v15 | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v16 |
| ef:activity/change/20260822T0600486828500000/365745 | concept_associations | ef:agent/carry_associations_onto_flows | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v16 | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v17 |
| ef:activity/change/20260822T0600486828500000/389561 | properties | ef:agent/normalise_property_values | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v17 | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v18 |
| ef:activity/change/20260822T0600486828500000/396764 | types | ef:agent/link_flows_to_their_substance | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v18 | ef:flow/ca1026ec-6911-47d5-9a39-b0e2f54340a1/v19 |