Ethyl (mesitylcarbonyl)phenylphosphinate
Everything that changed this flow. Back to the flow
e67b702a-e651-40ff-b743-64a6e467c52a
By field
13 fields| Field | Changes | Written by | Latest note |
|---|---|---|---|
| properties | 5 | enrich_references, normalise_property_values, opsin_iupac, rdkit_post_consensus, rdkit_pre_consensus | typed the way the ontology types it |
| altLabel | 3 | chebi_altlabels, consensus_match, strip_catalogue_altlabels | Removed 3 catalogue altLabel value(s): 'Doublecure 1256' (trade name), 'Irgacure 316' (trade name), 'LR 8893X' (grade code) |
| prefLabel | 2 | bootstrap_labels, normalize_name_case | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| cas_match_labels | 1 | consensus_match | group_key=ethyl(mesitylcarbonyl)phenylphosphinate||dimension=Environmental > media=Ground > geography=Agricultural; group_sources=['chebi', 'ec_inventory', 'pubchem']; cas_sources={'84434-11-7': ['chebi', 'ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-302a57ed6e482129: {'84434-11-7': 'exactMatch'} |
| concept_associations | 1 | carry_associations_onto_flows | associations resolved on the elementary layer |
| context | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to non-agricultural soil |
| context_iri | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to non-agricultural soil |
| name | 1 | bootstrap_labels | Purged legacy name field to enforce prefLabel usage |
| references | 1 | enrich_references | Added references with provenance; cas_numbers=['84434-11-7']; matched_chebi_ids=['http://purl.obolibrary.org/obo/CHEBI_188868']; candidate_pubchem_cids=[16205480, 66645384, 90735071]; selected_pubchem_cids=[16205480]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| skos_definition | 1 | enrich_references | Merged ChEBI/PubChem definitions into skos:definition |
| synonyms | 1 | bootstrap_labels | Removed legacy synonyms field in favor of structured labels |
| types | 1 | link_flows_to_their_substance | the substance's answer, copied onto its flow |
| unit_iri | 1 | unit_normalization | Unit IRI set from normalization of 'kg' |
Where several steps wrote one field, the last one won — and the log below shows the sequence.
Changes
20| # | Step | Field | From | To | Why |
|---|---|---|---|---|---|
| 10,575 | bootstrap_labels | prefLabel | — | [{"@value":"ethyl (mesitylcarbonyl)phenylphosphinate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_label… | Bootstrapped prefLabel from legacy name field |
| 10,576 | bootstrap_labels | name | ethyl (mesitylcarbonyl)phenylphosphinate | — | Purged legacy name field to enforce prefLabel usage |
| 10,577 | bootstrap_labels | synonyms | ["organic","ethylphenyl(2,4,6-trimethylbenzoyl)phosphinate","2,4,6-trimethylbenzoylethoxyphenylphosphineoxide","2,4,6-t… | [] | Removed legacy synonyms field in favor of structured labels |
| 187,758 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Ground","geography":"Non-agricultural"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to non-agricultural soil |
| 187,759 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-grou-noag | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to soil > Emissions to non-agricultural soil |
| 216,847 | unit_normalization | unit_iri | — | https://vocab.brightway.one/units/unit/KiloGM | Unit IRI set from normalization of 'kg' |
| 223,567 | normalize_name_case | prefLabel | [{"@value":"ethyl (mesitylcarbonyl)phenylphosphinate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_label… | [{"@value":"Ethyl (mesitylcarbonyl)phenylphosphinate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_label… | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| 237,251 | enrich_references | properties | {} | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C18H21O3P"… | Added ChEBI/PubChem properties (chebi_ids=1, pubchem_cids=1) |
| 237,252 | enrich_references | skos_definition | — | [] | Merged ChEBI/PubChem definitions into skos:definition |
| 237,253 | enrich_references | references | [] | [{"@id":"http://jglobal.jst.go.jp/en/redirect?Nikkaji_No=J297.672B","provenance":{"prov:wasGeneratedBy":"enrich_referen… | Added references with provenance; cas_numbers=['84434-11-7']; matched_chebi_ids=['http://purl.obolibrary.org/obo/CHEBI_188868']; candidate_pubchem_cids=[16205480, 66645384, 90735071]; selected_pubchem_cids=[16205480]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| 251,205 | rdkit_pre_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C18H21O3P"… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C18H21O3P"… | rdkit_pre_consensus from 'CCOP(=O)(C(=O)c1c(C)cc(C)cc1C)c1ccccc1'; added: monoisotopic_mass |
| 255,877 | chebi_altlabels | altLabel | [] | [{"@value":"[ethoxy(phenyl)phosphoryl]-(2,4,6-trimethylphenyl)methanone","@language":"en","source":{"prov:wasGeneratedB… | Added 1 ChEBI synonym(s) as altLabel from 1 linked ChEBI record(s) |
| 266,815 | consensus_match | altLabel | [{"@value":"[ethoxy(phenyl)phosphoryl]-(2,4,6-trimethylphenyl)methanone","@language":"en","source":{"prov:wasGeneratedB… | [{"@value":"[ethoxy(phenyl)phosphoryl]-(2,4,6-trimethylphenyl)methanone","@language":"en","source":{"prov:wasGeneratedB… | group_key=ethyl(mesitylcarbonyl)phenylphosphinate||dimension=Environmental > media=Ground > geography=Agricultural; cas=84434-11-7; added Common Chemistry CAS names as altLabel: 2,4,6-Trimethylbenzoyl-ethoxylphenylphosphine oxide, 2,4,6-Trimethylbenzoylethoxyphenylphosphine oxide, 2,4,6-Trimethylbenzoylphenylethoxyphosphine oxide, Darocur TPO-L, Doublecure 1256, Ethoxyphenyl(2,4,6-trimethylbenzoyl)phosphine oxide, Ethyl (2,4,6-trimethylbenzoyl)phenylphosphinate, Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate, Irgacure 316, Irgacure TPO-L, JRcure TPO-L, LR 8893X, Lucirin LR 8893X, Lucirin TPO Liquid, Lucirin TPO-L, Omnicure TPO-L, Omnirad TPO-I, Omnirad TPO-L, Phosphinic acid, <em>P</em>-phenyl-<em>P</em>-(2,4,6-trimethylbenzoyl)-, ethyl ester, Phosphinic acid, phenyl(2,4,6-trimethylbenzoyl)-, ethyl ester, Photoinitiator TEPO, Speedcure TPO-L, TPO-L; object_uuid=fo-302a57ed6e482129 |
| 266,816 | consensus_match | cas_match_labels | — | {"84434-11-7":"exactMatch"} | group_key=ethyl(mesitylcarbonyl)phenylphosphinate||dimension=Environmental > media=Ground > geography=Agricultural; group_sources=['chebi', 'ec_inventory', 'pubchem']; cas_sources={'84434-11-7': ['chebi', 'ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-302a57ed6e482129: {'84434-11-7': 'exactMatch'} |
| 276,390 | opsin_iupac | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C18H21O3P"… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C18H21O3P"… | opsin_iupac: set authoritative IUPAC name, SMILES, InChI from 'Ethyl (mesitylcarbonyl)phenylphosphinate' |
| 282,990 | rdkit_post_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C18H21O3P"… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C18H21O3P"… | rdkit_post_consensus from 'CCOP(=O)(C(=O)c1c(C)cc(C)cc1C)c1ccccc1'; confirmed: smiles_string, inchi2d_string, inchi2d_key_string, molecular_formula, molecular_mass, monoisotopic_mass |
| 289,457 | strip_catalogue_altlabels | altLabel | [{"@value":"[ethoxy(phenyl)phosphoryl]-(2,4,6-trimethylphenyl)methanone","@language":"en","source":{"prov:wasGeneratedB… | [{"@value":"[ethoxy(phenyl)phosphoryl]-(2,4,6-trimethylphenyl)methanone","@language":"en","source":{"prov:wasGeneratedB… | Removed 3 catalogue altLabel value(s): 'Doublecure 1256' (trade name), 'Irgacure 316' (trade name), 'LR 8893X' (grade code) |
| 374,907 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/e67b702a-e651-… | associations resolved on the elementary layer |
| 390,742 | normalise_property_values | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C18H21O3P"… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C18H21O3P"… | typed the way the ontology types it |
| 398,496 | link_flows_to_their_substance | types | — | ["https://w3id.org/chemrof/NeutralMolecule"] | the substance's answer, copied onto its flow |
PROV-O trail
20 activitiesOne activity per change: which version of the flow it consumed, and which it produced. The values are on the change with the same number — stored once, not twice.
| Activity | Field | Agent | Used | Generated |
|---|---|---|---|---|
| ef:activity/change/20260822T0600486828500000/10575 | prefLabel | ef:agent/bootstrap_labels | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v0 | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v1 |
| ef:activity/change/20260822T0600486828500000/10576 | name | ef:agent/bootstrap_labels | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v1 | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v2 |
| ef:activity/change/20260822T0600486828500000/10577 | synonyms | ef:agent/bootstrap_labels | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v2 | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v3 |
| ef:activity/change/20260822T0600486828500000/187758 | context | ef:agent/default_context_mapping | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v3 | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v4 |
| ef:activity/change/20260822T0600486828500000/187759 | context_iri | ef:agent/default_context_mapping | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v4 | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v5 |
| ef:activity/change/20260822T0600486828500000/216847 | unit_iri | ef:agent/unit_normalization | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v5 | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v6 |
| ef:activity/change/20260822T0600486828500000/223567 | prefLabel | ef:agent/normalize_name_case | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v6 | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v7 |
| ef:activity/change/20260822T0600486828500000/237251 | properties | ef:agent/enrich_references | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v7 | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v8 |
| ef:activity/change/20260822T0600486828500000/237252 | skos_definition | ef:agent/enrich_references | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v8 | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v9 |
| ef:activity/change/20260822T0600486828500000/237253 | references | ef:agent/enrich_references | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v9 | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v10 |
| ef:activity/change/20260822T0600486828500000/251205 | properties | ef:agent/rdkit_pre_consensus | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v10 | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v11 |
| ef:activity/change/20260822T0600486828500000/255877 | altLabel | ef:agent/chebi_altlabels | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v11 | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v12 |
| ef:activity/change/20260822T0600486828500000/266815 | altLabel | ef:agent/consensus_match | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v12 | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v13 |
| ef:activity/change/20260822T0600486828500000/266816 | cas_match_labels | ef:agent/consensus_match | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v13 | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v14 |
| ef:activity/change/20260822T0600486828500000/276390 | properties | ef:agent/opsin_iupac | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v14 | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v15 |
| ef:activity/change/20260822T0600486828500000/282990 | properties | ef:agent/rdkit_post_consensus | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v15 | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v16 |
| ef:activity/change/20260822T0600486828500000/289457 | altLabel | ef:agent/strip_catalogue_altlabels | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v16 | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v17 |
| ef:activity/change/20260822T0600486828500000/374907 | concept_associations | ef:agent/carry_associations_onto_flows | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v17 | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v18 |
| ef:activity/change/20260822T0600486828500000/390742 | properties | ef:agent/normalise_property_values | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v18 | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v19 |
| ef:activity/change/20260822T0600486828500000/398496 | types | ef:agent/link_flows_to_their_substance | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v19 | ef:flow/e67b702a-e651-40ff-b743-64a6e467c52a/v20 |