Tetramethyl Orthosilicate
Everything that changed this flow. Back to the flow
f1bf2167-2762-4ad2-b55f-b4a0e01d6d35
By field
13 fields| Field | Changes | Written by | Latest note |
|---|---|---|---|
| properties | 4 | enrich_references, normalise_property_values, rdkit_post_consensus, rdkit_pre_consensus | typed the way the ontology types it |
| altLabel | 2 | consensus_match, strip_catalogue_altlabels | Removed 9 catalogue altLabel value(s): 'CG 501' (grade code), 'KBM 04' (grade code), 'LS 540' (grade code), 'MZ 51' (grade code), 'NSC 67383' (registry code), 'T 1980' (grade code), 'TO 588' (grade code), 'TSL 8114' (grade code), 'WD 931' (grade code) |
| prefLabel | 2 | bootstrap_labels, normalize_name_case | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| cas_match_labels | 1 | consensus_match | group_key=tetramethylorthosilicate||dimension=Environmental > media=Air > strata=Aircraft cruise height; group_sources=['ec_inventory', 'pubchem']; cas_sources={'681-84-5': ['ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-b3c30ff19a4752b4: {'681-84-5': 'exactMatch'} |
| concept_associations | 1 | carry_associations_onto_flows | associations resolved on the elementary layer |
| context | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to urban air close to ground |
| context_iri | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to urban air close to ground |
| name | 1 | bootstrap_labels | Purged legacy name field to enforce prefLabel usage |
| references | 1 | enrich_references | Added references with provenance; cas_numbers=['681-84-5']; matched_chebi_ids=[]; candidate_pubchem_cids=[12682]; selected_pubchem_cids=[12682]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| skos_definition | 1 | enrich_references | Merged ChEBI/PubChem definitions into skos:definition |
| synonyms | 1 | bootstrap_labels | Removed legacy synonyms field in favor of structured labels |
| types | 1 | link_flows_to_their_substance | the substance's answer, copied onto its flow |
| unit_iri | 1 | unit_normalization | Unit IRI set from normalization of 'kg' |
Where several steps wrote one field, the last one won — and the log below shows the sequence.
Changes
18| # | Step | Field | From | To | Why |
|---|---|---|---|---|---|
| 13,858 | bootstrap_labels | prefLabel | — | [{"@value":"tetramethyl orthosilicate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:wasAtt… | Bootstrapped prefLabel from legacy name field |
| 13,859 | bootstrap_labels | name | tetramethyl orthosilicate | — | Purged legacy name field to enforce prefLabel usage |
| 13,860 | bootstrap_labels | synonyms | ["organometallic","tetramethylorthosilicate","dynasylan(r)m"] | [] | Removed legacy synonyms field in favor of structured labels |
| 194,166 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","strata":"Ground level","population_density":"Urban (>1000 people/square mil… | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to urban air close to ground |
| 194,167 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-grle-ur10pesq | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to urban air close to ground |
| 217,917 | unit_normalization | unit_iri | — | https://vocab.brightway.one/units/unit/KiloGM | Unit IRI set from normalization of 'kg' |
| 224,305 | normalize_name_case | prefLabel | [{"@value":"tetramethyl orthosilicate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:wasAtt… | [{"@value":"Tetramethyl Orthosilicate","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov:wasAtt… | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| 240,305 | enrich_references | properties | {} | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C4H12O4Si"… | Added ChEBI/PubChem properties (chebi_ids=0, pubchem_cids=1) |
| 240,306 | enrich_references | skos_definition | — | [] | Merged ChEBI/PubChem definitions into skos:definition |
| 240,307 | enrich_references | references | [] | [{"@id":"http://jglobal.jst.go.jp/en/redirect?Nikkaji_No=J36.490H","provenance":{"prov:wasGeneratedBy":"enrich_referenc… | Added references with provenance; cas_numbers=['681-84-5']; matched_chebi_ids=[]; candidate_pubchem_cids=[12682]; selected_pubchem_cids=[12682]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| 252,093 | rdkit_pre_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C4H12O4Si"… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C4H12O4Si"… | rdkit_pre_consensus from 'CO[Si](OC)(OC)OC'; added: molecular_mass, monoisotopic_mass |
| 272,473 | consensus_match | altLabel | [] | [{"@value":"CG 501","@language":"en","source":{"prov:wasGeneratedBy":"consensus_match","prov:wasAttributedTo":"consensu… | group_key=tetramethylorthosilicate||dimension=Environmental > media=Air > strata=Aircraft cruise height; cas=681-84-5; added Common Chemistry CAS names as altLabel: CG 501, Dynasil M, Dynasylan M, KBM 04, LS 540, MKC Silicate MS 39, MZ 51, Methyl Silicate 28, Methyl Silicate 39, Methyl Silicate 40, Methyl Silicate 51L, Methyl orthosilicate, Methyl silicate, Methyl silicate ((CH<sub>3</sub>)<sub>4</sub>SiO<sub>4</sub>), Methyl silicate ((MeO)<sub>4</sub>Si), NIC-C 5, NSC 67383, OCD-T 2, SIT 7510.0, Silane, tetramethoxy-, Silicic acid (H<sub>4</sub>SiO<sub>4</sub>), tetramethyl ester, Silicon methoxide (Si(OMe)<sub>4</sub>), Silicon tetramethoxide, Siluplex, T 1980, TMOS, TO 588, TSL 8114, Tetramethoxy orthosilicate, Tetramethoxysilane, Tetramethyl silicate, WD 931; object_uuid=fo-b3c30ff19a4752b4 |
| 272,474 | consensus_match | cas_match_labels | — | {"681-84-5":"exactMatch"} | group_key=tetramethylorthosilicate||dimension=Environmental > media=Air > strata=Aircraft cruise height; group_sources=['ec_inventory', 'pubchem']; cas_sources={'681-84-5': ['ec_inventory', 'pubchem']}; assigned CAS labels from group consensus; object_uuid=fo-b3c30ff19a4752b4: {'681-84-5': 'exactMatch'} |
| 283,960 | rdkit_post_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C4H12O4Si"… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C4H12O4Si"… | rdkit_post_consensus from 'CO[Si](OC)(OC)OC'; confirmed: smiles_string, inchi2d_string, inchi2d_key_string, molecular_formula, molecular_mass, monoisotopic_mass |
| 290,096 | strip_catalogue_altlabels | altLabel | [{"@value":"CG 501","@language":"en","source":{"prov:wasGeneratedBy":"consensus_match","prov:wasAttributedTo":"consensu… | [{"@value":"Dynasil M","@language":"en","source":{"prov:wasGeneratedBy":"consensus_match","prov:wasAttributedTo":"conse… | Removed 9 catalogue altLabel value(s): 'CG 501' (grade code), 'KBM 04' (grade code), 'LS 540' (grade code), 'MZ 51' (grade code), 'NSC 67383' (registry code), 'T 1980' (grade code), 'TO 588' (grade code), 'TSL 8114' (grade code), 'WD 931' (grade code) |
| 378,115 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/f1bf2167-2762-… | associations resolved on the elementary layer |
| 391,641 | normalise_property_values | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C4H12O4Si"… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C4H12O4Si"… | typed the way the ontology types it |
| 399,765 | link_flows_to_their_substance | types | — | ["https://w3id.org/chemrof/NeutralMolecule"] | the substance's answer, copied onto its flow |
PROV-O trail
18 activitiesOne activity per change: which version of the flow it consumed, and which it produced. The values are on the change with the same number — stored once, not twice.
| Activity | Field | Agent | Used | Generated |
|---|---|---|---|---|
| ef:activity/change/20260821T1302361922970000/13858 | prefLabel | ef:agent/bootstrap_labels | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v0 | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v1 |
| ef:activity/change/20260821T1302361922970000/13859 | name | ef:agent/bootstrap_labels | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v1 | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v2 |
| ef:activity/change/20260821T1302361922970000/13860 | synonyms | ef:agent/bootstrap_labels | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v2 | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v3 |
| ef:activity/change/20260821T1302361922970000/194166 | context | ef:agent/default_context_mapping | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v3 | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v4 |
| ef:activity/change/20260821T1302361922970000/194167 | context_iri | ef:agent/default_context_mapping | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v4 | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v5 |
| ef:activity/change/20260821T1302361922970000/217917 | unit_iri | ef:agent/unit_normalization | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v5 | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v6 |
| ef:activity/change/20260821T1302361922970000/224305 | prefLabel | ef:agent/normalize_name_case | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v6 | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v7 |
| ef:activity/change/20260821T1302361922970000/240305 | properties | ef:agent/enrich_references | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v7 | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v8 |
| ef:activity/change/20260821T1302361922970000/240306 | skos_definition | ef:agent/enrich_references | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v8 | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v9 |
| ef:activity/change/20260821T1302361922970000/240307 | references | ef:agent/enrich_references | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v9 | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v10 |
| ef:activity/change/20260821T1302361922970000/252093 | properties | ef:agent/rdkit_pre_consensus | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v10 | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v11 |
| ef:activity/change/20260821T1302361922970000/272473 | altLabel | ef:agent/consensus_match | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v11 | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v12 |
| ef:activity/change/20260821T1302361922970000/272474 | cas_match_labels | ef:agent/consensus_match | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v12 | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v13 |
| ef:activity/change/20260821T1302361922970000/283960 | properties | ef:agent/rdkit_post_consensus | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v13 | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v14 |
| ef:activity/change/20260821T1302361922970000/290096 | altLabel | ef:agent/strip_catalogue_altlabels | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v14 | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v15 |
| ef:activity/change/20260821T1302361922970000/378115 | concept_associations | ef:agent/carry_associations_onto_flows | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v15 | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v16 |
| ef:activity/change/20260821T1302361922970000/391641 | properties | ef:agent/normalise_property_values | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v16 | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v17 |
| ef:activity/change/20260821T1302361922970000/399765 | types | ef:agent/link_flows_to_their_substance | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v17 | ef:flow/f1bf2167-2762-4ad2-b55f-b4a0e01d6d35/v18 |