Bromo(ethyl)triphenylphosphorane
Everything that changed this flow. Back to the flow
fb885cbd-36c6-4341-b795-6c4ae84b371a
By field
13 fields| Field | Changes | Written by | Latest note |
|---|---|---|---|
| properties | 5 | enrich_references, normalise_property_values, opsin_iupac, rdkit_post_consensus, rdkit_pre_consensus | typed the way the ontology types it |
| altLabel | 2 | consensus_match, strip_catalogue_altlabels | Removed 1 catalogue altLabel value(s): 'SA 242' (grade code) |
| prefLabel | 2 | bootstrap_labels, normalize_name_case | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| cas_match_labels | 1 | consensus_match | group_key=bromo(ethyl)triphenylphosphorane||dimension=Environmental > media=Water > water_body=Surface water; group_sources=['ec_inventory']; cas_sources={'1530-32-1': ['ec_inventory']}; assigned CAS labels from group consensus; object_uuid=fo-352e43dd624918f5: {'1530-32-1': 'exactMatch'} |
| concept_associations | 1 | carry_associations_onto_flows | associations resolved on the elementary layer |
| context | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, indoor |
| context_iri | 1 | default_context_mapping | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, indoor |
| name | 1 | bootstrap_labels | Purged legacy name field to enforce prefLabel usage |
| references | 1 | enrich_references | Added references with provenance; cas_numbers=['1530-32-1']; matched_chebi_ids=[]; candidate_pubchem_cids=[73727, 159748, 53429621]; selected_pubchem_cids=[73727]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| skos_definition | 1 | enrich_references | Merged ChEBI/PubChem definitions into skos:definition |
| synonyms | 1 | bootstrap_labels | Removed legacy synonyms field in favor of structured labels |
| types | 1 | link_flows_to_their_substance | the substance's answer, copied onto its flow |
| unit_iri | 1 | unit_normalization | Unit IRI set from normalization of 'kg' |
Where several steps wrote one field, the last one won — and the log below shows the sequence.
Changes
19| # | Step | Field | From | To | Why |
|---|---|---|---|---|---|
| 1,218 | bootstrap_labels | prefLabel | — | [{"@value":"bromo(ethyl)triphenylphosphorane","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov… | Bootstrapped prefLabel from legacy name field |
| 1,219 | bootstrap_labels | name | bromo(ethyl)triphenylphosphorane | — | Purged legacy name field to enforce prefLabel usage |
| 1,220 | bootstrap_labels | synonyms | ["organic","ethyltriphenylfosfoniumbromide"] | [] | Removed legacy synonyms field in favor of structured labels |
| 200,826 | default_context_mapping | context | — | {"dimension":"Environmental","media":"Air","indoor":"Unknown"} | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, indoor |
| 200,827 | default_context_mapping | context_iri | — | https://vocab.brightway.one/flow-contexts/envi-air-indr-unkn | Mapped from context mapping for source=EF 3.1, source context Emissions > Emissions to air > Emissions to air, indoor |
| 213,741 | unit_normalization | unit_iri | — | https://vocab.brightway.one/units/unit/KiloGM | Unit IRI set from normalization of 'kg' |
| 221,372 | normalize_name_case | prefLabel | [{"@value":"bromo(ethyl)triphenylphosphorane","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov… | [{"@value":"Bromo(ethyl)triphenylphosphorane","@language":"en","source":{"prov:wasGeneratedBy":"bootstrap_labels","prov… | Title-cased words without internal capitals (preserved words with uppercase letters beyond the first character) |
| 228,344 | enrich_references | properties | {} | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C20H20BrP"… | Added ChEBI/PubChem properties (chebi_ids=0, pubchem_cids=1) |
| 228,345 | enrich_references | skos_definition | — | [] | Merged ChEBI/PubChem definitions into skos:definition |
| 228,346 | enrich_references | references | [] | [{"@id":"https://chem.echa.europa.eu/100.014.749","provenance":{"prov:wasGeneratedBy":"enrich_references.pubchem_identi… | Added references with provenance; cas_numbers=['1530-32-1']; matched_chebi_ids=[]; candidate_pubchem_cids=[73727, 159748, 53429621]; selected_pubchem_cids=[73727]; formula_similarity_expected=[]; pubchem_selection_rule=curated_cas_then_formula_similarity_then_prefer_chebi_aligned_when_unambiguous_else_keep_all_cas_matches; single_cas_commonchem_link=yes |
| 248,651 | rdkit_pre_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C20H20BrP"… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C20H20BrP"… | rdkit_pre_consensus from 'CC[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Br-]'; added: molecular_mass, monoisotopic_mass |
| 264,447 | consensus_match | altLabel | [] | [{"@value":"Ethyltriphenylphosphonium bromide","@language":"en","source":{"prov:wasGeneratedBy":"consensus_match","prov… | group_key=bromo(ethyl)triphenylphosphorane||dimension=Environmental > media=Water > water_body=Surface water; cas=1530-32-1; added Common Chemistry CAS names as altLabel: Ethyltriphenylphosphonium bromide, Phosphonium, ethyltriphenyl-, bromide, Phosphonium, ethyltriphenyl-, bromide (1:1), SA 242, TEP, TEP (onium compound), Triphenylethylphosphonium bromide; object_uuid=fo-352e43dd624918f5 |
| 264,448 | consensus_match | cas_match_labels | — | {"1530-32-1":"exactMatch"} | group_key=bromo(ethyl)triphenylphosphorane||dimension=Environmental > media=Water > water_body=Surface water; group_sources=['ec_inventory']; cas_sources={'1530-32-1': ['ec_inventory']}; assigned CAS labels from group consensus; object_uuid=fo-352e43dd624918f5: {'1530-32-1': 'exactMatch'} |
| 273,772 | opsin_iupac | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C20H20BrP"… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C20H20BrP"… | opsin_iupac: set authoritative IUPAC name, SMILES, InChI from 'Ethyltriphenylphosphonium bromide' |
| 280,151 | rdkit_post_consensus | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C20H20BrP"… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C20H20BrP"… | rdkit_post_consensus from 'CC[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[Br-]'; confirmed: smiles_string, inchi2d_string, inchi2d_key_string, molecular_formula, molecular_mass, monoisotopic_mass |
| 287,495 | strip_catalogue_altlabels | altLabel | [{"@value":"Ethyltriphenylphosphonium bromide","@language":"en","source":{"prov:wasGeneratedBy":"consensus_match","prov… | [{"@value":"Ethyltriphenylphosphonium bromide","@language":"en","source":{"prov:wasGeneratedBy":"consensus_match","prov… | Removed 1 catalogue altLabel value(s): 'SA 242' (grade code) |
| 381,440 | carry_associations_onto_flows | concept_associations | [] | [{"@type":"xkos:ConceptAssociation","xkos:sourceConcept":{"@id":"https://vocab.brightway.one/ef/3.1/flow/fb885cbd-36c6-… | associations resolved on the elementary layer |
| 388,048 | normalise_property_values | properties | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C20H20BrP"… | {"https://w3id.org/chemrof/molecular_formula":{"@id":"https://w3id.org/chemrof/molecular_formula","@value":["C20H20BrP"… | typed the way the ontology types it |
| 394,639 | link_flows_to_their_substance | types | — | ["https://w3id.org/chemrof/ChemicalSalt"] | the substance's answer, copied onto its flow |
PROV-O trail
19 activitiesOne activity per change: which version of the flow it consumed, and which it produced. The values are on the change with the same number — stored once, not twice.
| Activity | Field | Agent | Used | Generated |
|---|---|---|---|---|
| ef:activity/change/20260820T1812399309960000/1218 | prefLabel | ef:agent/bootstrap_labels | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v0 | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v1 |
| ef:activity/change/20260820T1812399309960000/1219 | name | ef:agent/bootstrap_labels | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v1 | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v2 |
| ef:activity/change/20260820T1812399309960000/1220 | synonyms | ef:agent/bootstrap_labels | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v2 | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v3 |
| ef:activity/change/20260820T1812399309960000/200826 | context | ef:agent/default_context_mapping | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v3 | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v4 |
| ef:activity/change/20260820T1812399309960000/200827 | context_iri | ef:agent/default_context_mapping | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v4 | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v5 |
| ef:activity/change/20260820T1812399309960000/213741 | unit_iri | ef:agent/unit_normalization | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v5 | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v6 |
| ef:activity/change/20260820T1812399309960000/221372 | prefLabel | ef:agent/normalize_name_case | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v6 | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v7 |
| ef:activity/change/20260820T1812399309960000/228344 | properties | ef:agent/enrich_references | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v7 | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v8 |
| ef:activity/change/20260820T1812399309960000/228345 | skos_definition | ef:agent/enrich_references | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v8 | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v9 |
| ef:activity/change/20260820T1812399309960000/228346 | references | ef:agent/enrich_references | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v9 | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v10 |
| ef:activity/change/20260820T1812399309960000/248651 | properties | ef:agent/rdkit_pre_consensus | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v10 | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v11 |
| ef:activity/change/20260820T1812399309960000/264447 | altLabel | ef:agent/consensus_match | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v11 | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v12 |
| ef:activity/change/20260820T1812399309960000/264448 | cas_match_labels | ef:agent/consensus_match | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v12 | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v13 |
| ef:activity/change/20260820T1812399309960000/273772 | properties | ef:agent/opsin_iupac | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v13 | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v14 |
| ef:activity/change/20260820T1812399309960000/280151 | properties | ef:agent/rdkit_post_consensus | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v14 | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v15 |
| ef:activity/change/20260820T1812399309960000/287495 | altLabel | ef:agent/strip_catalogue_altlabels | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v15 | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v16 |
| ef:activity/change/20260820T1812399309960000/381440 | concept_associations | ef:agent/carry_associations_onto_flows | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v16 | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v17 |
| ef:activity/change/20260820T1812399309960000/388048 | properties | ef:agent/normalise_property_values | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v17 | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v18 |
| ef:activity/change/20260820T1812399309960000/394639 | types | ef:agent/link_flows_to_their_substance | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v18 | ef:flow/fb885cbd-36c6-4341-b795-6c4ae84b371a/v19 |